1. 毕业设计（论文）的内容和要求

内容：研究气体扩散电极结构和孔道设计，支撑体的选择、催化层厚度以及碳黑和PTFE不同比例对过氧化氢产量以及电流效率的影响，优化参数，确定最佳电流、曝气量、电解液的循环液速以及pH值 要求：(1)熟练掌握电芬顿反应的基本原理；（2）熟练掌握气体扩散电极的制备方法；（3）熟练掌握过氧化氢的浓度测量；

2. 参考文献

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Zhou, Electrogeneration of hydrogen peroxide for electro-Fenton system by oxygen reduction using chemically modified graphite felt cathode, Sep. Purif. Technol. 111 (2013) 131-136. [11] G.Q. Zhang, F.L. Yang, M.M. Gao, X.H. Fang, L.F. Liu, Electro-Fenton degradation of azo dye using polypyrrole/anthraquinonedisulphonate composite film modified graphite cathode in acidic aqueous solutions, Electrochim. Acta. 53 (2008) 5155-5161. [12] O. Scialdone, A. Galia, S. Sabatino, Electro-generation of H2O2 and abatement of organic pollutant in water by an electro-Fenton process in a microfluidic reactor, Electrochem. Commun. 26 (2013) 45-47. [13] M.H. Zhou, Q.H. Yu, L.C. Lei, G. Barton, Electro-Fenton method for the removal of methyl red in an efficient electrochemical system, Sep. Purif. Technol. 57 (2007) 380-387. [14] G.S. Xia, Y.H. Lu, H.B. Xu, An energy-saving production of hydrogen peroxide via oxygen reduction for electro-Fenton using electrochemically modified polyacrylonitrile-based carbon fiber brush cathode, Sep. Purif. Technol. 156 (2015) 553-560. [15] W. Ren, D.Y. Tang, X.S. Lu, J. Sun, M. Li, S. Qiu, D.J. Fan, Novel multilayer ACF@rGO@OMC cathode composite with enhanced activity for electro-Fenton degradation of phthalic acid esters, Ind. Eng. Chem. Res. 55 (2016) 11085-11096. [16] W.R.P. Barros, R.M. Reis, R.S. Rocha, M.R.V. Lanza, Electrogeneration of hydrogen peroxide in acidic medium using gas diffusion electrodes modified with cobalt (II) phthalocyanine, Electrochim. Acta. 104 (2013) 12-18. [17] F.L. Silva, R.M. Reis, W.R.P. Barros, R.S. Rocha, M.R.V. Lanza, Electrogeneration of hydrogen peroxide in gas diffusion electrodes: Application of iron (II) phthalocyanine as a modifier of carbon black, J. Electroanal. Chem. 722-723 (2014) 32-37. [18] W.R.P. Barros, T. Ereno, A.C. Tavares, M.R.V. Lanza, In situ electrochemical generation of hydrogen peroxide in alkaline aqueous solution by using an unmodified gas diffusion electrode, Chemelectrochem. 2 (2015) 714-719. [19] F.K. Yu, M.H. Zhou, X.M. Yu, Cost-effective electro-Fenton using modified graphite felt that dramatically enhanced on H2O2 electro-generation without external aeration, Electrochim. Acta. 163 (2015) 182-189. [20] J.N. Tian, A.M. Olajuyin, T.Z. Mu, M.H. Yang, J.M. Xing, Efficient degradation of rhodamine B using modified graphite felt gas diffusion electrode by electro-Fenton process, Environ. Sci. Pollut. R. 23 (2016) 11574-11583. [21] J.N. Tian, J.X Zhao, A.M. Olajuyin, M.M. Sharshar, T.Z Mu, M.H. Yang, J.M. Xing, Effective degradation of rhodamine B by electro-Fenton process, using ferromagnetic nanoparticles loaded on modified graphite felt electrode as reusable catalyst: in neutral pH condition and without external aeration, Environ. Sci. Pollut. R. 23 (2016) 15471-15482. [22] C. Zhang, L. Zhou, J. 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De Souza, I. Gaubeur, R.T.S. Oliveira, V.S. Antonin, G.R.P. Malpass, R.S. Rocha, M.L. Calegaro, M.R.V. Lanza, M.C. Santos, Low content cerium oxide nanoparticles on carbon for hydrogen peroxide electrosynthesis, Appl. Catal. A-Gen. 411-412 (2012) 1-6. [27] A.D. Pozzo, L.D. Palma, C. Merli, E. Petrucci, An experimental comparison of a graphite electrode and a gas diffusion electrode for the cathodic production of hydrogen peroxide, J. Appl. Electrochem. 35 (2005) 413-419. [28] M. Sudoh, H. Kitaguchi, K. Koide, Electrochemical production of hydrogen peroxide by reduction of oxygen, J. Chem. Eng. Jpn. 18 (1985) 409-414. [29] Y. Zhang, M.M. Gao, S.G. Wang, W.Z. Zhou, Y.H. Sang, X.H. Wang, Integrated electro-Fenton process enabled by a rotating Fe3O4/gas diffusion cathode for simultaneous generation and activation of H2O2, Electrochim. Acta. 231 (2017) 694-704.

3. 毕业设计（论文）进程安排

3月份：熟悉环境、看相关文献了解制备方法，下一步进行实验制备。

4月份：实验室制备气体扩散电极，表征与分析。

5月份：进行结果讨论分析以及论文撰写。