MOPs@MIL-101复合材料的制备及其性能研究任务书
2020-06-26 19:48:32
1. 毕业设计(论文)的内容和要求
(1) 结合课题的研究,加深对基本理论、基本知识以及课题背景知识的理解。
(2) 能尽快进入课题研究领域展开思考,加强分析问题解决问题的能力。
(3) 学会检索中外文文献,阅读文献并归纳总结,为以后的学习或工作提供条件。
2. 参考文献
[1] Yu Y, Zhang Q, Xie J, et al. Engineering the Architectural Diversity of Heterogeneous Metallic Nanocrystals [J]. Nat. Commun., 2013, 4: 1454. [2] Liu T F, Chen Y P, Yakovenko A A, et al. Interconversion Between Discrete and a Chain of Nanocages: Self-Assembly via a Solvent-Driven, Dimension-Augmentation Strategy [J]. J. Am. Chem. Soc., 2012, 134 (42): 17358-17361. [3] Peng Y, Gong T, Zhang K, et al. Engineering Chiral Porous Metal-Organic Frameworks for Enantioselective Adsorption and Separation [J]. Nat. Commun., 2014, 5: 4406. [4] Perry J J t, Perman J A, Zaworotko M J. Design and Synthesis of Metal-Organic Frameworks Using Metal-Organic Polyhedra as Supermolecular Building Blocks [J]. Chem. Soc. Rev, 2009, 38 (5): 1400-1417. [5] Olenyuk B, Levin M D, Whiteford J A, et al. Self-Assembly of Nanoscopic Dodecahedra from 50 Predesigned Components[J]. J. Am. Chem. Soc., 1999, 121(44): 10434-10435. [6] Levin M D, Stang P J. Insights into the Mechanism of Coordination-Directed Self-Assembly[J]. J. Am. Chem. Soc., 2000, 122(30): 7428-7429. [7] Klein E, Ferrand Y, Barwell N P, et al. Solvent Effects in Carbohydrate Binding by Synthetic Receptors: Implications for the Role of Water in Natural Carbohydrate Recognition[J]. Angew. Chem. Int. Ed., 2008, 47(14): 2693-2696. [8] Ferrand Y, Crump M P, Davis A P. Synthetic Lectin Analog for Biomimetic Disaccharide Recognition[J]. Science, 2007, 318(5850): 619-624. [9] Yoshizawa M, Tamura M, Fujita M. Diels-Alder in Aqueous Molecular Hosts: Unusual Regioselectivity and Efficient Catalysis[J]. Science, 2006, 312(5771): 251-257. [10] Perez E V, Balkus K J, Ferraris J P, et al. Metal-Organic Polyhedra 18 Mixed-Matrix Membranes for Gas Separation [J]. J. Membr. Sci., 2014, 463: 82-93. [11] Li J-R, Timmons D J, Zhou H-C. Interconversion between Molecular Polyhedra and Metal-Organic Frameworks [J]. J. Am. Chem. Soc., 2009, 131 (18): 6368-6369. [12] Han Y, Li J R, Xie Y, et al. Substitution Reactions in Metal-Organic Frameworks and Metal-Organic Polyhedra [J]. Chem. Soc. Rev., 2014, 43 (16): 5952-5981.
3. 毕业设计(论文)进程安排
2018.2.26-2018.3.10 查阅收集文献资料,了解课题背景;并整理资料,撰写毕业论文开题报告; 2018.3.10-2018.5.1 熟悉相关仪器,准备实验药品,开始制备复合物; 2018.5.1-2018.5.15 对复合物进行各种表征,研究其应用,并且撰写中期自查表; 2018.5.15-2018.6.1 整理并补充实验数据,为撰写论文作准备; 2018.6.1-2018.6.15 撰写论文,准备论文答辩。