基于金属有机框架光催化剂的合成及降解有机染料性能研究任务书
2020-06-26 19:50:29
1. 毕业设计(论文)的内容和要求
内容:合成mof材料,然后用水热合成法合成出mof基异质结光催化剂,用xrd、uv、sem等表征材料,最后将催化剂用于降解。
要求:要求本科生掌握对催化剂的合成过程,及其一系列的表征。
掌握文献的检索查阅。
2. 参考文献
1. Zheng, M.; Ding, Y.; Yu, L.; Du, X.; Zhao, Y., In Situ Grown Pristine Cobalt Sulfide as Bifunctional Photocatalyst for Hydrogen and Oxygen Evolution. Advanced Functional Materials 2017, 27 (11), 1605846. 2. Zhang, K.; Qian, S.; Kim, W.; Kim, J. K.; Sheng, X.; Lee, J. Y.; Park, J. H., Double 2-dimensional H 2 -evoluting catalyst tipped photocatalyst nanowires: A new avenue for high-efficiency solar to H 2 generation. Nano Energy 2017, 34, 481-490. 3. Mei, Z.; Zhang, B.; Zheng, J.; Yuan, S.; Zhuo, Z.; Meng, X.; Chen, Z.; Amine, K.; Yang, W.; Wang, L. W.; Wang, W.; Wang, S.; Gong, Q.; Li, J.; Liu, F. S.; Pan, F., Tuning Cu dopant of Zn 0.5 Cd 0.5 S nanocrystals enables high-performance photocatalytic H 2 evolution from water splitting under visible-light irradiation. Nano Energy 2016, 26, 405-416. 4. Chen, J.; Wu, X. J.; Yin, L.; Li, B.; Hong, X.; Fan, Z.; Chen, B.; Xue, C.; Zhang, H., One-pot synthesis of CdS nanocrystals hybridized with single-layer transition-metal dichalcogenide nanosheets for efficient photocatalytic hydrogen evolution. Angewandte Chemie 2015, 54 (4), 1210-4. 5. Lan, M.; Guo, R.-M.; Dou, Y.; Zhou, J.; Zhou, A.; Li, J.-R., Fabrication of porous Pt-doping heterojunctions by using bimetallic MOF template for photocatalytic hydrogen generation. Nano Energy 2017, 33, 238-246. 6. Gu, Z. G.; Li, D. J.; Zheng, C.; Kang, Y.; Woll, C.; Zhang, J., MOF-Templated Synthesis of Ultrasmall Photoluminescent Carbon-Nanodot Arrays for Optical Applications. Angewandte Chemie 2017, 56 (24), 6853-6858. 7. Chambers, M. B.; Wang, X.; Ellezam, L.; Ersen, O.; Fontecave, M.; Sanchez, C.; Rozes, L.; Mellot-Draznieks, C., Maximizing the Photocatalytic Activity of Metal-Organic Frameworks with Aminated-Functionalized Linkers: Substoichiometric Effects in MIL-125-NH2. Journal of the American Chemical Society 2017, 139 (24), 8222-8228. 8. An, Y.; Liu, Y.; An, P.; Dong, J.; Xu, B.; Dai, Y.; Qin, X.; Zhang, X.; Whangbo, M.-H.; Huang, B., NiIICoordination to an Al-Based Metal-Organic Framework Made from 2-Aminoterephthalate for Photocatalytic Overall Water Splitting. Angewandte Chemie International Edition 2017, 56 (11), 3036-3040. 9. Yu, X.; Cohen, S. M., Photocatalytic Metal-Organic Frameworks for Selective 2,2,2-Trifluoroethylation of Styrenes. Journal of the American Chemical Society 2016, 138 (38), 12320-3. 10. Wu, Z. L.; Wang, C. H.; Zhao, B.; Dong, J.; Lu, F.; Wang, W. H.; Wang, W. C.; Wu, G. J.; Cui, J. Z.; Cheng, P., A Semi-Conductive Copper-Organic Framework with Two Types of Photocatalytic Activity. Angewandte Chemie 2016, 55 (16), 4938-42.
3. 毕业设计(论文)进程安排
2016-02-24#8212;03-10 查阅国内外有关文献,拟订实验方案。
2016-03-10#8212;03-20 翻译外文文献,并撰写文献综述。
2016-03-20#8212;04-10 按照拟定的实验方案依次进行实验。