新型二维材料MXene膜的制备表征 及醇水分离性能任务书
2020-06-26 19:52:20
1. 毕业设计(论文)的内容和要求
本次毕业论文的主要内容是新型二维材料MXene(Ti3C2Tx)膜的制备,并对其进行表征。
1、理解渗透汽化的基本概念、原理、实验流程图以及影响其性能的主要因素; 2、了解渗透汽化膜的基本分类及其所应用的分离体系; 3、 熟悉二维材料MXene及其膜制备及表征的常规方法; 4、合理安排实验进程,工作时间不迟到早退; 5、实验认真仔细,对实验现象进行详细的记录,定期对实验数据进行总结,及时调整实验方案; 6、工作积极主动,勤于思考,做好实验室安全卫生工作。
2. 参考文献
[1] Yee KangOng, Gui MinShi.,Ngoc LieuLe,et al. Recent membrane development for pervaporatio process[J]. Progress in Polymer Science.2016,57,1#8211;31. [2] 陈翠仙, 韩宾兵, 朗宁威. 渗透蒸发和渗透汽化 [M]. 北京: 化学工业出版社, 2004. [3] Bowen TC., Noble RD, Falconer JL. Fundamentals and applications of pervaporation through zeolite membranes [J]. J. Membr. Sci.2004, 245, 1-33. [4] Geim A K, Novoselov K S. The rise of graphene[J]. Nature materials, 2007, 6(3) [5]M. Naguib, M. Kurtoglu, V. Presser, J. Lu, J. Niu, M. Heon, L.Hultman, Y. Gogotsi, M. W. Barsoum, Two-Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2[J].Adv. Mater. 2011, 23,4248 #8211; 4253 [6] Ghidiu, M., Lukatskaya, M. R., Zhao, M.-Q.,Gogotsi, Y. Barsoum, M. W. Conductive twodimensional titanium carbide ”clay#8217; with high volumetric capacitance[J]. Nature.2014,516, 78#8211;81 [7] Karlsson, L. H., Birch, J., Halim, J., Barsoum, M. W. Persson, P. O. Atomically resolved structural and chemical investigation of single MXene sheets[J]. Nano Lett. 2015,15, 4955#8211;4960. [8] Mashtalir, O. et al. Dye adsorption and decomposition on two-dimensional titanium carbide in aqueous media[J]. J. Mater. Chem. A ,2014,2, 14334#8211;14338 [9] Babak Anasori, Maria R. Lukatskaya and Yury Gogotsi. 2D metal carbides and nitrides (MXenes) for energy storage[J]. nature reviews,2017,2,16098,1-17 [10] Wang, K. et al. Fabrication and thermal stability of two-dimensional carbide Ti3C2 nanosheets[J]. Ceram. Int.2016,42, 8419#8211;8424 [11] Gusev, A. Rempel, A. in Materials Science of Carbides, Nitrides and Borides (eds Gogotsi, Y. Andrievski, R. A.) 47#8211;64 (Springer, 1999) [12] Chang E. Ren, Kelsey B. Hatzell, Mohamed Alhabeb,Zheng Ling, Khaled A. Mahmoud,and Yury Gogotsi. Charge- and Size-Selective Ion Sieving Through Ti3C2Tx Mxene Membranes[J].J. Phys. Chem. Lett. 2015, 6, 4026#8722;4031 [13] Li Ding, Yanying Wei, Yanjie Wang, Hongbin Chen, J#252;rgen Caro,and Haihui Wang. A Two-Dimensional Lamellar Membrane: MXene Nanosheet Stacks[J]. Angew. Chem. Int. Ed. 2017, 56, 1 #8211; 6 [14] Xiaoli Wu, Lan Hao, Jiakui Zhang, Xiang Zhang, Jingtao Wang n, Jindun Liu. Polymer-Ti3C2Tx composite membranes to overcome the trade-off in solvent resistant nanofiltration for alcohol-based system[J]. Journal of Membrane Science ,2016,515 , 175#8211;18
3. 毕业设计(论文)进程安排
18.3.10~18.4.10 文献调研,开题报告 18.4.10~18.5.21 开展实验工作 18.5.21~18.5.28 中后期实验阶段及数据收集 18.5.28~18.6.10 数据整理,撰写论文