改性的铁磁性钙钛矿氧化物在有机废水降解的高级氧化技术中的研究任务书
2020-06-26 19:52:32
1. 毕业设计(论文)的内容和要求
学会采用各种文献检索手段对特定课题进行检索的方法,培养阅读中外文献资料的能力。
2. 培养综合运用所学专业知识分析、解决实际问题的能力。
3.培养独立开展实验研究、独立思考和分析问题与现象,并解决问题,完成课题的工作能力。
2. 参考文献
[1] N.N. Tusar, D. Maucec, M. Rangus, I. Arcon, M. Mazaj, M. Cotman, A. Pintar, V. Kauci c, Manganese functionalized silicate nanoparticles as a Fenton-type catalyst for water purification by advanced oxidation processes (AOP), Adv. Funct. Mater. 22 (2012) 820#8211;826. [2] G.P. Anipsitakis, D.D. Dionysiou, Degradation of organic contaminants in water with sulfate radicals generated by the conjunction of peroxymonosulfate with cobalt, Environ. Sci. Technol. 37 (2003) 4790#8211;4797. [3] S. Yuan, Y. Fan, Y. Zhang, M. Tong, P. Liao, Pd-catalytic in situ generation of H2O2 from H2 and O2 produced by water electrolysis for the efficient electro-fenton degradation of rhodamine B, Environ. Sci. Technol. 45 (2011) 8514#8211;8520. [4] G.P. Anipsitakis, D.D. Dionysiou, Transition metal/UV-based advanced oxidation technologies for water decontamination, Appl. Catal. B 54 (2004) 155#8211;163. [5] G.P. Anipsitakis, D.D. Dionysiou, Radical generation by the interaction of transition metals with common oxidants, Environ. Sci. Technol. 38 (2004) 3705#8211;3712. [6] E. Saputra, S. Muhammad, H. Sun, H.M. Ang, M.O. Tade, S. Wang, Different crystallographic one-dimensional MnO2 nanomaterials and their superior performance in catalytic phenol degradation, Environ. Sci. Technol. 47 (2013) 5882#8211;5887. [7] X. Chen, J. Chen, X. Qiao, D. Wang, X. Cai, Performance of nano-Co3O4/peroxymonosulfate system: kinetics and mechanism study using Acid Orange 7 as a model compound, Appl. Catal. B 80 (2008) 116#8211;121. [8] P. Shi, X. Dai, H. Zheng, D. Li, W. Yao, C. Hu, Synergistic catalysis of Co3O4 and graphene oxide on Co3O4/GO catalysts for degradation of Orange II in water by advanced oxidation technology based on sulfate radicals, Chem. Eng. J. 240 (2014) 264#8211;270. [9] Q. Yang, H. Choi, Y. Chen, D.D. Dionysiou, Heterogeneous activation of peroxymonosulfate by supported cobalt catalysts for the degradation of 2,4-dichlorophenol in water: the effect of support cobalt precursor, and UV radiation, Appl. Catal. B 77 (2008) 300#8211;307. [10] S. Yuan, X. Mao, A.N. Alshawabkeh, Efficient degradation of TCE in groundwater using Pd and electro-generated H2 and O2: a shift in pathway from hydrodechlorination to oxidation in the presence of ferrous ions, Environ. Sci. Technol. 46 (2012) 3398#8211;3405. [11] A.D. Bokare, W. Choi, Review of iron-free Fenton-like systems for activating H2O2 in advanced oxidation processes, J. Hazard. Mater. 275 (2014) 121#8211;135. [12] S. Rahim Pouran, A.A. Abdul Raman, W.M.A. Wan Daud, Review on the application of modified iron oxides as heterogeneous catalysts in Fenton reactions, J. Cleaner Prod. 64 (2014) 24#8211;35. [13] S. Yuan, P. Liao, A.N. Alshawabkeh, Electrolytic manipulation of persulfate reactivity by iron electrodes for trichloroethylene degradation in groundwater, Environ. Sci. Technol. 48 (2014) 656#8211;663. [14] C. Liang, Z.S. Wang, C.J. Bruell, Influence of pH on persulfate oxidation of TCE at ambient temperatures, Chemosphere 66 (2007) 106#8211;113. [15] C. Liang, H.-W. Su, Identification of sulfate and hydroxyl radicals in thermally activated persulfate, Ind. Eng. Chem. Res. 48 (2009) 5558#8211;5562. [16] O.S. Furman, A.L. Teel, R.J. Watts, Mechanism of base activation of persulfate, Environ. Sci. Technol. 44 (2010) 6423#8211;6428. [17] J.A. Khan, X. He, N.S. Shah, H.M. Khan, E. Hapeshi, D. Fatta-Kassinos, D.D. Dionysiou, Kinetic and mechanism investigation on the photochemical degradation of atrazine with activated H2O2, S2O82#8722; and HSO5#8722;, Chem. Eng. J. 252 (2014) 393#8211;403. [18] X. He, A.A. de la Cruz, K.E. O#8217;Shea, D.D. Dionysiou, Kinetics and mechanisms of cylindrospermopsin destruction by sulfate radical-based advanced oxidation processes, Water Res. 63 (2014) 168#8211;178. [19] 刘继凤,刘继永,朱进勇. 浅谈工业废水中难降解有机污染物处理技术级发展方向[J]. 环境科学与管理,2008,33(4):120-122. [20] 张伟红,王晓鹏,潘齐,等. 催化湿式氧化法处理对硝基酚废水[J]. 山东化工,2008(03):24-25.
3. 毕业设计(论文)进程安排
1-4周:阅读相关文献,了解专业背景,完成翻译。
2.5-8周:熟悉实验室的仪器设备,掌握基本的制备过程。
3.9-12周:采用xrd、sem、bet、tem等对粉体进行表征,测试材料的各种基本性质。