1. 毕业设计（论文）的内容和要求

1、调查研究、阅读文献资料和收集资料的能力； 2、理论分析、制定设计工作方案的能力 3、培养学生自己动手做实验的能力，研究反应条件，分析处理实验结果数据的能力； 4、撰写设计说明书和论文报告的能力 5、语言表达、思辨能力、阐述观点准确、清楚回答问题的能力

2. 参考文献

(1) OSTROWSKI S, DOBROWOLSKI J C. Side-chain alkylation of toluene with propene over a basic catalyst : A DFT study . J. Mol. Catal. A-Chem. 2008, 293, 86-96. (2) Alabi, W., Atanda, L., Jermy, R., Al-Khattaf, S. Kinetics of toluene alkylation with methanol catalyzed by pure and hybridized HZSM-5 catalysts. Chem. Eng. J. 2012, 195-196, 276-288. (3) Al-Khattaf, S., Rabiu, S., Tukur, N. M., Alnaizy, R. Kinetics of toluene methylation over USY-zeolite catalyst in a riser simulator. Chem. Eng. J. 2008, 139, 622-30. (4) CUNDY C S, COX P A. The Hydrothermal Synthesis of Zeolites:#8201; History and Development from the Earliest Days to the Present Time. Chem. Rev. 2003, 34, 663-702. (5) Liu, K., Xie, S., Xu, G., Li, Y., Liu, S., Xu, L. Effects of NaOH solution treatment on the catalytic performances of MCM-49 in liquid alkylation of benzene with ethylene. Appl Catal A-Gen. 2010, 383, 102-11. (6) Liu, Y., Xu, L., Xu, B., Li, Z., Jia, L., Guo, W. Toluene alkylation with 1-octene over supported heteropoly acids on MCM-41 catalysts . J. Mol. Catal. A-Chem. #8194;2009, 297, 86-92. (7) Llanos, A., Melo, L., Avendantilde;o, F., Montes, A., Brito, J. L. Synthesis and characterization of HPW/MCM-41 (Si) and HPW/MCM-41 (Si/Al) catalysts: Activity for toluene alkylation with 1-dodecene. Catal. Today. 2008, 133, 20-7. (8) XUE B, LI Y, DENG L. Selective synthesis of p -xylene by alkylation of toluene with dimethyl carbonate over MgO-modified MCM-22. Catal. Commun. 2010, 10, 1609-14. (9) Wang, C., Fan, L., Shen, Y., Liu, D., Xu, S. Gas-Phase Synthesis of Para-tert-Butyltoluene from Toluene and tert-Butyl Alcohol over H-Mordenite Catalyst. Chem. React. Eng. Tech. 2012, 28, 50-56. (10) Mogera,U., Gedda,M., George, S. J., Kulkarni G.U. A Supramolecular Nanofiber-Based Passive Memory Device for Remembering Past Humidity. ACS Appl. Mater. Inter. DOI: 10.1021/acsami.7b10732 (11) Yang, Y., Ding, J., Xu, C., Zhu, W., Wu, P. An insight into crystal morphology-dependent catalytic properties of MOR-type titanosilicate in liquid-phase selective oxidation. J. Catal. 2015, 325, 101-110. (12) Finocchio, E., Montanari, T., Resini, C., Busca, G. Spectroscopic characterization of cobalt-containing solid catalysts. J. Mol. Catal. A-Chem. 2003, 204, 535-544. (13) Silva, T. Q., Santos, M. B. D., Santiago, A. A. C., Santana, D. O., Cruz, F. T., Andrade, H. M. C., Mascarenhas, A. J.S. Gas phase glycerol oxidative dehydration over bifunctional V/H-zeolite catalysts with different zeolite topologies. Catal. Today. 2017, 289, 38-46. (14) Pietrogiacomi D, Campa M C, Occhiuzzi M. Selective catalytic reduction of N2O with CH4, on Ni-MOR: A comparison with Co-MOR and Fe-MOR catalysts. Catal. Today. 2014, 227, 116-122. (15) Sun, K., Su, W., Fan, F., Feng, Z., Jansen, T. A., van Santen, R. A. Li C. Location of Mg cations in mordenite zeolite studied by IR spectroscopy and density functional theory simulations with a CO adsorption probe . J. Phys. Chem. A. 2008, 112, 1352-8. (16)Xie, J., Wen, H., Zhang, W., Zhou, Y., Wang, J. Mg2 -derived mesoporous ultra-high silica twelve-membered-ring basic zeolites: straightforward synthesis and catalytic performance. Crystengcomm. 2016, 18, 1164-73. (17) Corma, A., Nemeth, L. T., Renz, M., Valencia, S. Sn-zeolite beta as a heterogeneous chemoselective catalyst for Baeyer-Villiger oxidations. Nature. 2001, 412, 423. (18) Janiszewska, E., Kowalak, S., Supronowicz, W., Roessner, F. Synthesis and properties of stannosilicates. Micropor. Mesopor. Mat. 2009, 117(1#8211;2): 423-30. (19) Pillai, U. R., Sahle-Demessie, E. Sn-exchanged hydrotalcites as catalysts for clean and selective Baeyer#8211;Villiger oxidation of ketones using hydrogen peroxide. J. Mol. Catal. A-Chem. 2003, 191, 93-100. (20) Wolf, P., Valla, M., Rossini, A. J., Comas‐Vives, A., N#250;ntilde;ez‐Zarur, F., Malaman, B.,Lesage, A., Emsley, L., Coperet, C., Hermans, I. NMR Signatures of the Active Sites in Sn-β#8197;Zeolite dagger . Angew. Chem. Int. Edit. 2014, 53, 10179-83. (21) Fejes, P., Nagy, J. B., Kov#225;cs, K., Vank#243;, G. Synthesis of tin(IV) silicalites (MFI) and their characterization A Mouml;ssbauer and MAS NMR spectroscopy study. Appl. Catal. A-Gen. 1996, 145(1#8211;2): 155-84. (22) Gu, J., Wu, Y., Jin, Y., Wang, J. Hydrothermal incorporation of Ce(La) ions into the framework of ZSM-5 by a multiple pH-adjusting co-hydrolysis. J. Porous. Mat. 2013, 20, 7-13. (23) Fan, W., Duan, R. G., Yokoi, T., Wu, P., Kubota, Y., Tatsumi, T. Synthesis, crystallization mechanism, and catalytic properties of titanium-rich TS-1 free of extraframework titanium species. J. Am. Chem. Soc. 2008, 130, 10150-64. （24）Zhang, W., Xie, J., Hou, W., Liu, Y., Zhou, Y., Wang, J. One-pot template-free synthesis of cu-mor zeolite towards efficient catalyst support for aerobic oxidation of 5-hydroxymethylfurfural under ambient pressure. Acs Applied Materials Interfaces, (2016) 8 (35), 23122. (24) Ma, Z., Xie, J., Zhang, J., Zhang, W., Zhou, Y., Wang, J. Mordenite zeolite with ultrahigh SiO2/Al2O3 ratio directly synthesized from ionic liquid-assisted dry-gel-conversion. Micropor. Mesopor. Mat. 2016, 224, 17-25. (25) P#243;polo, M. G. D., Mullan, C. L., Holbrey, J. D., Hardacre, C., Ballone, P. Ion association in [bmim][PF6]/naphthalene mixtures: An experimental and computational study. J. Am. Chem. Soc. 2008, 130, 7032-41. (26) Gutel, T., Santini, C. C., P#225;dua, A. A., Fenet, B., Chauvin, Y., Canongia Lopes, J. N., Bayard, F., Costa Gomes, M. F., Pensado, A. Interaction between the π-system of toluene and the imidazolium ring of ionic liquids: a combined NMR and molecular simulation study. J. Phys. Chem. B. 2008, 113, 170-7. (27) P#225;dua AA, Costa Gomes MF, Canongia Lopes JN. Molecular solutes in ionic liquids: a structural perspective. Accounts. chem. res. 2007, 40, 1087-96. (28) Campbell, P. S., Santini, C. C., Bouchu, D., Fenet, B., Philippot, K., Chaudret, B., Padua A. A., Chauvin, Y. A novel stabilisation model for ruthenium nanoparticles in imidazolium ionic liquids: in situ spectroscopic and labelling evidence. Phys. Chem. Chem. Phys. 2010, 12, 4217-23. (29) Lu, B., Tsuda, T., Sasaki, H., Oumi, Y., Itabashi, K., Teranishi, T., Sano, T. Effect of Aluminum Source on Hydrothermal Synthesis of High-Silica Mordenite in Fluoride Medium, and Its Thermal Stability. J. Cheminformatics. 2004, 35, 15. (30) Zhou, D., Lu, X., Xu, J., Yu, A., Li, J.,Deng, F., Xia, Q. Dry Gel Conversion Method for the Synthesis of Organic#8211;Inorganic Hybrid MOR Zeolites with Modifiable Catalytic Activities. Chem. Mate. 2012, 24, 4160-5. (31)N. Narender, K. S. K. Reddy, K. V. V. K. Mohan, S. J Kulkarni, A. Koeckritrz, K. V. Raghavan, J. Porous Mat., 18, 337 (2011) (31) Wu, P., Komatsu, T., Yashima, T. IR and MAS NMR Studies on the Incorporation of Aluminum Atoms into Defect Sites of Dealuminated Mordenites . J. phys. Chem. 1995, 99, 10923-31. (32) Fejes, P., Nagy, J. B., Kov#225;cs, K., Vank#243;, G. Synthesis of tin(IV) silicalites (MFI) and their characterization A Mouml;ssbauer and MAS NMR spectroscopy study. Appl. Catal.A-Gen. 1996, 145, 155-184. （33）Ｒamaswamy A V，Mal N K． Hydroxylation of phenol over Sn-silicalite-1 molecular sieve: Solvent effects ［J］． J Mol Catal A: Chem，1996，105( 3) : 149－158．

3. 毕业设计（论文）进程安排

2018年2月-3月 查找相关文献，熟悉课题研究背景，并完成一篇外文翻译 2018年3月-4月 完成开题报告，制定实验计划 2018年4月-5月 进行实验得出数据 2018年5月-6月 完成论文