1. 毕业设计（论文）的内容和要求

查阅相关查阅相关文献与专业书籍了解目前对甲醇裂解制氢的研究现状，了解已有成果以及存在的问题，对论文的研究方向有较深入的认识。

培养学生独立思考及动手做实验的能力，养成良好的科研习惯。

学会查找和阅读文献；学会应用相关实验设备和分析仪器。

2. 参考文献

[1]. TONELLI F，GORRIZ O，TARDITI A，CORNAGLIA L，ARRU′ A L，ABELLO M C. Activity and stability of a CuO/CeO2 catalyst for methanol steam reforming[J]. Int J Hydrogen Energy，2015，40(39): 13379-13387. [2]. AMIRI T Y and MOGHADDAS J. Cogeled copper-silica aerogel as a catalyst in hydrogen production from methanol steam reforming[J]. Int J Hydrogen Energy，2015，40(3): 1472-1480. [3]. SIRIRUANG C，CHAROJROCHKUL S，TOOCHINDA P. Hydrogen production from methanol-steam reforming at low temperature over Cu-Zn/ZrO2-doped Al2O3[J]. Monatsh Chem.，2016，147(7): 1143-1151. [4]. VERENDEL J J and DINE′ R P. Efficient，low temperature production of hydrogen from methanol[J]. Chem Cat Chem，2013，5(10): 2795-2797. [5]. LYTKINA A A，ZHILYAEVA N A，ERMILOVA M M，OREKHOVA N V，YAROSLAVTSEV A B. Influence of the support structure and composition of Ni-Cu-based catalysts on hydrogen production by methanol steam reforming[J]. Int J Hydrogen Energy，2015，40(31): 9677-9684. [6]. YANG R X，CHUANG K H，WEY M Y. Hydrogen production through methanol steam reforming：Effect of synthesis parameters on Ni-Cu/CaO-SiO2 catalysts activity[J]. Int J Hydrogen Energy，2014，39(34): 19494-19501. [7]. MATSUMURA Y，TANAKA K，TODE N，YAZAWA T，HARUTA M. Catalytic methanol decomposition to carbon monoxide and hydrogen over nickel supported on silica[J]. J Mol Catal A: Chem，2000，152(1-2): 157 - 165. [8]. PAPAVASILIOU J，AVGOUROPOULOS G，IOANNIDES T. Steam reforming of methanol over copper-manganese spinel oxide catalysts[J]. Catal Commun，2005，6(7): 497-501. [9]. CHEN H W，YIN A Y，GUO X Y，DAI W L，FAN K N. Sodium hydroxide-sodium oxalate-assisted co-precipitation of highly active and stable Cu/ZrO2 catalyst in the partial oxidation of methanol to hydrogen[J]. Catal Lett，2009，131(3-4): 632-642. [10]. 张雄伟，储伟，王晓东，杨维慎，盛世善，张涛. 氧化铝担载的贵金属铱基催化剂的制备及其对甲醇裂解反应的催化性能[J]. 催化学报，2006，27(10): 863-867. （ZHANG Xiong-wei，CHU Wei，WANG Xiao-dong，YANG Wei-shen，SHENG Shi-shan，ZHANG Tao. Preparation of alumina-supported nobel metal iridium catalysts and their catalytic performance for methanol decomposition[J]. Chinese J Catal，2006，27(10): 863-867.） [11]. 李雪，王晓文，赵明，刘建英，龚茂初，陈耀强. 钙改性的Pd/CeO2-ZrO2-Al2O3催化剂催化甲醇裂解反应[J]. 催化学报，2011， 32(11): 1739-1746. （LI Xue，WANG Xiao-wen，ZHAO Ming，GONG Mao-chu，CHEN Yao-qiang. Ca-modified Pd/CeO2-ZrO2-Al2O3 catalysts for methanol decomposition[J]. Chinese J Catal，2011，32(11): 1739-1746.） [12]. YONG S T，OOI C W，CHAI S P，YU F，WU X S. Review of methanol reforming-Cu-based catalysts，surface reaction mechanisms，and reaction schemes[J]. Int J Hydrogen Energy，2013，38(22) : 9541 -9552． [13]. YAAKOB Z，KAMARUDIN S K，DAUD W R W，YOSFIAH M R，LIM K L，KAZEMIAN H. Hydrogen production by methanol-steam reforming using Ni-Mo-Cu/gamma-alumina trimetallic catalysts [J]. Asia-Pac J Chem Eng，2010，5(6) : 862 -868． [14]. 倪哲明，毛江洪，潘国祥，胥倩，李小年. Pd催化甲醇裂解制氢的反应机理[J]．物理化学学报，2009，25(5) : 876-882． （NI Zhe-ming，MAO Jiang-hong，PAN Guo-xiang，XU Qian，LI Xiao-nian. Mechanism of palladium-catalyzed methanol decomposition for hydrogen production[J].Acta Phys-Chim Sin，2009，25(5) : 876-882） [15].ZHAO S，YUE H R，XUE J J，ZHAO Y J，WANG B，GENG Y C，LV J，WANG S P，GONG J L，MA X B. Chemoselective synthesis of ethanol via hydrogenation of dimethyl oxalate on Cu/SiO2: Enhanced stability with boron dopant [J]. J Catal，2013，297(1): 142-150. [16]. CHEN L F，GUO P J，QIAO M H，YAN S R，LI H X，SHEN W，XU H L，FAN K N. Cu/SiO2 catalysts prepared by the ammonia-evaporation method：Texture，structure，and catalytic performance in hydrogenation of dimethyl oxalate to ethylene glycol[J]. J Catal，2008，257(1): 172-180. [17]. LI F J，WANG L G，HAN X，CAO Y，HE P，LI H Q. Selective hydrogenation of ethylene carbonate to methanol and ethylene glycol over Cu/SiO2 catalysts prepared by ammonia evaporation method[J]. Int J Hydrogen Energy，2017，42(4): 2144-2156. [18]. ZHANG C C，WANG D H，ZHU M Y，YU F，DAI B. Effect of different nano-sized silica sols as supports on the structure and properties of Cu/SiO2 for hydrogenation of dimethyl oxalate[J]. Catalysts，2017，7(3): 75. [19]. YOU Y W，LEE D G，YOON K Y，MOON D K，KIM S M，LEE C H. H2 PSA purifier for CO removal from hydrogen mixtures[J]. Int J Hydrogen Energy，2012，37(23):18175-18186. [20]. HUANG Z W，CUI F，XUE J J，ZUO J L，CHEN J，XIA C G. Cu/SiO2 catalysts prepared by hom- and heterogeneous deposition-precipitation methods: Texture，structure，and catalytic performance in the hydrogenolysis of glycerol to 1,2-propanediol[J]. Catal Today，2012，183(1): 42-51. [21]. 王新雷，马奎，郭丽红，丁彤，程庆鹏，田野，李新刚. 蒸氨法制备铜硅催化剂的二甲醚水蒸气重整制氢性能[J]. 物理化学学报，2017，33(8):1699-1708. （WANG Xin-lei，MA Kui，GUO Li-hong，DING Tong，CHENG Qing-peng，TIAN Ye，LI Xin-gang. Catalytic performance for hydrogen production through steam reforming of dimethyl ether over silica supported copper catalysts synthesized by ammonia evaporation method[J]. Acta Phys-Chim Sin，2017，33(8):1699-1708.）

3. 毕业设计（论文）进程安排

起讫日期 设计（论文）各阶段工作 2018年3月初 ：阅读相关文献； 2018年3月到5月：完成相关实验； 2018年5月到6月：整理数据并用Origin等化工软件进行数据处理、分析； 2018年6月： 完成论文的撰写，准备答辩。