氯化液中贵金属的回收任务书
2020-07-01 21:11:48
1. 毕业设计(论文)的内容和要求
氯化液是高锡阳极泥经酸浸脱铜后,以氯酸钠为氧化剂将固体中的贵金属浸出而得到的液体。
液体中含有80-100mg/l的au,150-180mg/l的ag,35-50mg/l的pd及其他金属元素,经济价值相当可观。
本课题研究溶液中贵金属的综合回收工艺,从而找到一种技术上可行、经济上合理的回收贵金属的最佳工艺路线。
2. 参考文献
[1]. Ailiang Chen, Zhiwei Peng, Jiann-Yang Hwang, Yutian Ma, Xuheng Liu, Xingyu Chen. Recovery of Silver and Gold from Copper Anode Slimes[J]. JOM, 2015, 67(2):493-502. [2]. Bin Hu , Man He , Beibei Chen. Nanometer-sized materials for solid-phase extraction of trace elements[J].Anal Bioanal Chem, 2015,407:2685#8211;2710. [3]. Weizhi Zeng, Shijie Wang, and Michael L. Free. Experimental Studies of the Effects of Anode Composition and Process Parameters on Anode Slime Adhesion and Cathode Copper Purity by Performing Copper Electrore#64257;ning in a Pilot-Scale Cell[J]. Metallurgical and Materials Transactions B.2016,47(5):3178-3191. [4]. Bin Li, ShenGen Zhang, Kun Zhang, De-An Pan, Jian-Jun Tian, Duan-Ting Zhang. Preparation of pure SnO2 powders from tin slag of printed circuit boards waste[J]. Rare Met.2014,33(6):749#8211;753 [5].Andreas#160;Filzwieser,Iris#160;Filzwieser#160;and#160;Stefan#160;Konetschnik.New#160;Technology#160;for#160;Electrorefining#160;of#160;Copper[J].JOM,2012,64(11):1290-1295. [6]. B#252;nyamin D#246;nmez, Fatih Fevim, and Fabxi #199;olah. A Study on Resovery of Gold from Desopperized Anode Slime[J].Chem. Eng. Technol.2001,24(1):91-95. [7]. Zhiyuan Ma, Hongying Yang, Songtao Huang, Yang L#252;, and Liu Xiong. Ultra fast microwave-assisted leaching for the recovery of copper and tellurium from copper anode slime[J]. International Journal of Minerals, Metallurgy and Materials.2015.122(6):582. [8]. Keqiang Qiu,Deqiang Lin,and Xuelin Yang. Vacuum Evaporation Technology for Treating Antimony-Rich Anode Slime[J].JOM.2012,64(11),1321-1325. [9]Atefeh Khaleghi, Sattar Ghader and Dariush Afzali.Ag recovery from copper anode slime by acid leaching at atmospheric pressure to synthesize silver nanoparticles[J].International Journal of Mining Science and Technology,2014,24(02):251-257. [10].Dong Li ,Xueyi Guo ,Zhipeng Xu, Runze Xu and Qiming Feng.Metal values separation from residue generated in alkali fusion-leaching of copper anode slime[J].Hydrometallurgy,2016,162 (2):290-294. [11]. 柯家骏,涂桃枝,李希明.湿法冶金从铜阳极泥中回收金银及其他金属[J].化工冶金. 1983,(03),47-50. [12]. 浦恩彬, 张俊.真空冶金在铅阳极泥回收稀贵金属中的工艺研究[J].云南冶金.2010,(05),40-43,68. [13]. 杜三保.国内外铜阳极泥处理方法综述[J].中国物资再生.1997,(02),16-19. [14].温宝臣. 国外铜铅阳极泥处理近况[J].贵金属.1977,(02),61-69. [15]. 宾万达,陈希鸿,陈庆郑,卢宜源. 铜阳极泥湿法冶金残渣的综合利用[J].矿冶工程.1988(04),46-49. [16].邬建辉,刘刚,王刚,张文宏,苏涛,魏涛.从复杂碲铜物料中回收碲的工艺研究[J].矿冶工程.2014,34(04),104-107. [17].张增伦.焊锡阳极泥湿法处理[J].稀有金属与硬质合金.1993,113,299-302. [18].俎小凤,王夏.铜萃余液综合回收铜、锌试验研究[J].选矿与冶炼.2013,34(02),50-54. [19].王吉坤,张博亚.阳极泥现代综合利用技术[M].北京:冶金工业出版社,2008. [20]黎鼎鑫,王永录.贵金属提取与精炼[M].长沙:中南大学出版社,2003.
3. 毕业设计(论文)进程安排
2017.12.25~2018.03.17查阅资料,翻译外文资料,编写开题报告; 2018.03.18~2018.05.19实验阶段 2018.03.20~2018.06.09实验数据整理、撰写毕业论文。