离子液体无限稀释时的热力学性质研究任务书
2020-04-21 16:57:33
1. 毕业设计(论文)的内容和要求
近年来,术语离子液体(il)已经定义了一系列完全由熔点低于373k的离子构成的物质。
多种il在室温下甚至在远低于该温度的温度下保持液态。
在它们独特的特性中,能够溶解各种各样的化合物,在常规工艺条件下可忽略不计的蒸气压,宽的液体范围,以及随意定制其化学结构以更好地匹配给定目标的可能性是特别值得注意的。
2. 参考文献
1. Heacute;ctor Rodr#305;guez , Joan F. Brennecke "Temperature and Composition Dependence of the Density and Viscosity of Binary Mixtures of Water Ionic Liquid " J. Chem. Eng. Data 2006, 51, 2145-2155. 2. Mohammed Taghi Zafarani-Moattar , Roghayeh Majdan-Cegincara "Viscosity, Density, Speed of Sound, and Refractive Index of Binary Mixtures of Organic Solvent Ionic Liquid, 1-Butyl-3-methylimidazolium Hexafluorophosphate at 298.15 K " J. Chem. Eng. Data 2007, 52, 2359-2364 3. Hemayat Shekaari, Mohammed Taghi Zafarani-Moattar, Saeid Faraji, Masumeh Mokhtarpour "Thermophysical properties of ionic liquid, 1 ethyl-3-methylimidazolium ethyl sulfate in organic solvents at dilute region " Journal of Molecular Liquids 269 (2018) 547#8211;555. 4. Erika Vata#353;cˇin, Vladim#237;r Dohnal "Thermodynamic properties of aqueous solutions of [EMIM] thiocyanate and [EMIM] dicyanamide " J. Chem. Thermodynamics 106 (2017) 262#8211;275. 5. Jia-Zhen Yang, Zhi-Heng Zhang, Da-Wei Fang, Ji-Guang Li, Wei Guan, Jian Tong "Studies on enthalpy of solution for ionic liquid: The system of 1-methyl-3-ethylimidazolium tetrafluoroborate (EMIBF4) "Fluid Phase Equilibria 247 (2006) 80#8211;83. 6. Marcin Durski, Prathieka Naidoo, Deresh Ramjugernath, Urszula Domanska, "Thermodynamics and activity coefficients at infinite dilution for organic solutes in the ionic liquid 1-butyl-1-methylpyrrolidinium dicyanamide," Fluid Phase Equilibria 473 (2018) 175-182. 7. Mark#233;ta Havlov#225;, Vladim#237;r Dohnal, "Thermodynamics of aqueous solutions of ionic liquids composed of [BMPYR] or [BMIM] cations and tetraflate or dicyanamide anions " J. Chem. Thermodynamics 121 (2018) 129#8211;144. 8. Erika Vata#353;cˇin, Vladim#237;r Dohnal "Thermophysical properties of aqueous solutions of the 1-ethyl-3-methylimidazolium tricyanomethanide ionic liquid " J. Chem. Thermodynamics 89 (2015) 169#8211;176. 9. Indrajit Das, Bharath kumar Chennuri, V. Ramkumar, Ramesh L. Gardas "Understanding the solvation behavior of tetramethylguanidinium based ionic liquids in dilute aqueous solutions through apparent molar properties " Journal of Molecular Liquids 242 (2017) 129#8211;136. 10. Leila Mohammadi, Abdollah Omrani, "Volumetric and optical properties of sulfolane (TMS) 1, 5-pentanediol binary solutions " Journal of Molecular Liquids 241 (2017) 163#8211;172. 11. Chunyan Ma , Aatto Laaksonen , Chang Liu, Xiaohua Lu, Xiaoyan Ji, "The Peculiar Effect of Water on Ionic Liquids and Deep Eutectic Solvents," Chem. Soc. Rev.,2018, 47, 8685--8720. 12. Phuoc H. Lam, Anh T. Tran, Dustin J. Walczyk, Alexandra M. Miller, Lei Yu. Conductivity, viscosity, and thermodynamic properties of propylene carbonate solutions in ionic liquids. Journal of Molecular Liquids 246 (2017) 215#8211;220. 13. Francisco Pena-Pereira , Jacek Namiesacute;nik. Ionic Liquids and Deep Eutectic Mixtures: Sustainable Solvents for Extraction Processes. ChemSusChem 2014, 7, 1784 #8211; 1800. 14. Ernesto Vercher, Francisco J. Llopis, Vicenta Gonz#225;lez-Alfaro, Pablo J. Miguel, Vicent Orchill#233;s, Volumetric properties, viscosities and refractive indices of binary liquid mixtures of tetrafluoroborate-based ionic liquids with methanol at several temperatures. J. Chem. Thermodynamics 90 (2015) 174#8211;184.
3. 毕业设计(论文)进程安排
2019.2.8-2019.2.28 查阅资料,熟悉研究方向,文献翻译。
2019.3.1-2019.3.18 熟悉实验仪器,以及相关的实验流程,并完成题报告及其相关部分。
2019.3.19-2019.4.10 相关实验数据测量并完成中期小结及其相关部分。