Ni1#8722;xCuxO纳米线阵列的合成及其电催化氧化氨基硼烷性能任务书
2020-04-21 16:58:11
1. 毕业设计(论文)的内容和要求
文献综述能够比较详尽地总结电催化氨基硼烷氧化反应的研究意义和催化剂性能的进展,包括用于燃料电池反应的优势、催化剂类型、结构组成、以及不同形状、组成的贵催化剂纳米晶体对电催化氨基硼烷氧化反应活性的影响。
提出本课题采用廉价非贵金属催化剂的研究意义。
详细列出实验所用试剂和分析仪器,实验方法具有一定独创性,杜绝简单重复前人的工作,能够独立提出本课题实验设计方案。
2. 参考文献
[1] 毛永志,张翀,李永伟,其鲁.电动车及其能源系统的发展 [J]. 物理化学学报,2007, (Supp.): 107~112. [2] Zhan W W, Zhu Q L, Xu Q. Dehydrogenation of Ammonia Borane by Metal Nanoparticle Catalysts [J]. ACS Catal. 2016, (6): 6892~6905. [3] Peng B, Chen J. Ammonia Borane as an Efficient and Lightweight Hydrogen Storage Medium [J]. Energy Environ Sci. 2008, (1): 479~483. [4] Yao C F, Yang H X, Zhuang L, Ai X P, Cao Y L, Lu J T. A Preliminary Study of Direct Borazane Fuel Cell [J]. J Power Sources. 2007, (165): 125~127. [5] Zhang X B, Han S, Yan J M, Chandra M, Shioyama H, Yasuda K, Kuriyama N, Kobayashi T, Xu Q. Boettcher S W. A New Fuel Cell Using Aqueous Ammonia-Borane as the Fuel [J]. J Power Sources. 2007, (168): 167~171. [6] Martins J I, Nunes M C. Comparison of the Electrochemical Oxidation of Borohydride and Dimethylamine Borane on Platinum Electrodes: Implication for Direct Fuel Cells [J]. J Power Sources. 2008, (175): 244~249. [7] Zhang X, Han S, Yan J, Shioyama H, Kuriyama N, Kobayashi T, Xu Q. Electrochemical Oxidation of Ammonia Borane on Gold Electrode [J]. Int J Hydrogen Energy. 2009, (34): 174~179. [8] Naglez L C, Rohan J F. Nanoporous Gold Catalyst for Direct Ammonia Borane Fuel Cells [J]. J Electrochem Soc. 2011, (158): B772~B778. [9] Zhang X B, Yan J M, Han S, Shioyama H, Xu Q. Magnetically Recyclable Fe@Pt Core#8722;Shell Nanoparticles and Their Use as Electrocatalysts for Ammonia Borane Oxidation: The Role of Crystallinity of the Core [J]. J Am Chem Soc. 2009, (131): 2778~2779. [10] Olu P Y, Deschamps F, Caldarella G, Chatenet M, Job N. Investigation of Platinum and Palladium as Potential Anodic Catalysts for Direct Borohydride and Ammonia Borane Fuel Cells [J]. J Power Sources. 2015, (297): 492~503. [11] Zadick A, Dubau L, Artyushkova K, Serov A, Atanassov P, Chatenet M. Ni-Based Electrocatalysts for Ammonia Borane Oxidation: Enabling Materials for Carbon-Free-Fuel Direct Liquid Alkaline Fuel Cell Technology [J]. Nano Energy. 2017, (37): 248~259.
3. 毕业设计(论文)进程安排
2019, 2, 25 #8210; 2019, 3, 8:查阅翻译文献,深入理解研究纳米结构非贵金属电催化剂的合成意义,在清洁、可再生能源转化中的应用价值和前景,纳米材料合成方法、物理性质。
撰写本研究方向的文献综述。
2019, 3, 11 #8210; 2019, 5, 24:熟悉并掌握实验仪器设备的使用与操作,掌握水热/溶剂热、高温热解合成纳米材料的实验方法、溶液配制方法,进行合成实验与产物的分析测试,优化实验条件(温度,配体封盖试剂选取等),选用不同反应物合成三维纳米结构ni1#8722;xcuxo/导电基底(碳纤维纸)一体化的催化电极,并进行电催化氨基硼烷氧化的研究。