1. 毕业设计（论文）的内容和要求

文献综述能够比较详尽地总结电催化分解水的研究意义和ni基双过渡金属硒化物纳米结构电解水催化剂的进展，包括ni基双3d过渡金属催化剂的成本低廉和高活性优势、纳米结构与组成可调控特性、组成对电解水催化活性的影响。

提出本课题采用廉价ni基双过渡金属硒化物纳米催化剂的研究意义。

详细列出实验所用试剂和分析仪器，实验方法具有一定独创性，杜绝简单重复前人的工作，能够独立提出本课题实验设计方案。

2. 参考文献

[1] Fabbri E, Habereder A, Waltar K, K#246;tz R, Schmidt T J. Developments and Perspectives of Oxide-Based Catalysts for the Oxygen Evolution Reaction [J]. Catal Sci Technol. 2014, (4): 3800～3821. [2] Seh Z W, Kibsgaard J, Dickens C F, Chorkendorff I, N#248;rskov J K, Jaramillo T F. Combining Theory and Experiment in Electrocatalysis: Insights into Materials Design [J]. Science. 2017, (355): eaad4998. [3] Suen N T, Hung S F, Quan Q, Zhang N, Xu Y J, Chen H M. Electrocatalysis for the Oxygen Evolution Reaction: Recent Development and Future Perspectives [J]. Chem Soc Rev. 2017, (46): 337～365. [4] Han L, Dong S, Wang E. Transition-Metal (Co, Ni, and Fe)-Based Electrocatalysts for the Water Oxidation Reaction [J]. Adv. Mater. 2016, (28): 9266～9291. [5] De S, Zhang J, Luque R, Yan N. Ni-Based Bimetallic Heterogeneous Catalysts for Energy and Environmental Applications [J]. Energy Environ Sci. 2016, (9): 3314～3347. [6] Wang A L, Xu H, Li G R. NiCoFe Layered Triple Hydroxides with Porous Structures as High-Performance Electrocatalysts for Overall Water Splitting [J]. ACS Energy Lett. 2016, (1): 445～453. [7] Ni B, Wang X. Edge Overgrowth of Spiral Bimetallic Hydroxides Ultrathin-Nanosheets for Water Oxidation [J]. Chem Sci. 2015, (6): 3572～3576. [8] Xu X, Song F, Hu X. A Nickel Iron Diselenide-Derived Efficient Oxygen-Evolution Catalyst [J]. Nature Commun. 2016, (7): 12324. [9] Nai J, Lu Y, Yu L, Wang X, Lou X W. Formation of Ni#8211;Fe Mixed Diselenide Nanocages as a Superior Oxygen Evolution Electrocatalyst [J]. Adv Mater. 2017, (29): 1703870. [10] Wang Z, Li J, Tian X, Wang X, Yu Y, Owusu K A, He L, Mai L. Porous Nickel#8211;Iron Selenide Nanosheets as Highly Efficient Electrocatalysts for Oxygen Evolution Reaction [J]. ACS Appl Mater Interfaces. 2016, (8): 19386～19392. [11] Xia C, Jiang Q, Zhao C, Hedhili M N, Alshareef H N. Selenide-Based Electrocatalysts and Scaffolds for Water Oxidation Applications [J]. Adv Mater. 2016, (28): 77～85. [12] Fang Z, Peng L, Lv H, Zhu Y, Yan C, Wang S, Kalyani P, Wu X, Yu G. Metallic Transition Metal Selenide Holey Nanosheets for Efficient Oxygen Evolution Electrocatalysis [J]. ACS Nano. 2017, (11): 9550～9557. [13] Yu J, Cheng G, Luo W. 3D Mesoporous Rose-Like Nickel-Iron Selenide Microspheres as Advanced Electrocatalysts for the Oxygen Evolution Reaction [J]. Nano Res. 2018, (11): 2149～2158.

3. 毕业设计（论文）进程安排

2019, 2, 25 #8210; 2019, 3, 8：查阅翻译文献，深入理解研究纳米结构ni基双3d过渡金属催化剂的合成意义，在催化电解水中的应用价值和前景，纳米材料合成方法、物理性质。

撰写本研究方向的文献综述。

2019, 3, 11 #8210; 2019, 5, 24：熟悉并掌握实验仪器设备的使用与操作，掌握水热/溶剂热、高温热解合成纳米材料的实验方法、溶液配制方法，进行合成实验与产物的分析测试，优化实验条件(温度，配体封盖试剂选取等)，选用不同反应物合成三维纳米结构ni1#8722;xfexse2/导电基底(碳纤维纸)一体化的催化电极，并进行电催析氧反应的研究。