1. 毕业设计（论文）的内容和要求

1、学习实验室规范实验操作和安全相关知识并熟知紧急情况处理的方法。

2、查阅与本课题相关的国内外文献，了解钨锆固体酸的物化性质。

3、制备pt/mgo/wo3-zro2催化剂； 4、熟悉并学会操作固定床催化反应装置，学会使用气相色谱仪分析反应产物； 5、学习催化剂表面性质的研究方法和实验方法。

2. 参考文献

[1]. Zhu S H.Gao X Q. et al., Alkaline metals modified Pt#8211;H4SiW12O40/ZrO2 catalysts for the selective hydrogenolysis of glycerol to 1,3-propanediol [J]. Applied Catalysis B: Environmental, 2013. 140-141: 60-67. [2]. Gounder R., Hydrophobic microporous and mesoporous oxides as Broslash;nsted and Lewis acid catalysts for biomass conversion in liquid water [J]. Catal. Sci. Technol, 2014. 4(9): 2877-2886. [3]. Lin X Z. Ren T Z.Yuan Z Y., Mesoporous zirconium phosphonate materials as efficient water-tolerable solid acid catalysts [J]. Catalysis Science Technology, 2015. 5(3): 1485-1494. [4]. Zhou W. Luo J. Wang Y., et al., WOx domain size, acid properties and mechanistic aspects of glycerol hydrogenolysis over Pt/WOx/ZrO2 [J]. Applied Catalysis B: Environmental, 2019. 242: 410-421. [5]. 杨笑,陈长林. 磷酸根表面修饰对钨锆复合氧化物载铂催化剂的影响[J]. 高校化学工程学报, 2017. 31(6): 1349-1355. [6]. Xiong H F, et al., Graphitic-Carbon Layers on Oxides: Toward Stable Heterogeneous Catalysts for Biomass Conversion Reactions [J]. Angewandte Chemie International Edition, 2015. 54(27): 7939-7943. [7]. Yu J, Si Z C, et al., NH3-SCR activity, hydrothermal stability and poison resistance of a zirconium phosphate/Ce0.5Zr0.5O2 catalyst in simulated diesel exhaust [J]. RSC ANXANCES, 2015. 5(102): 83594-83599. [8] Xiong, H. H.N. Pham, A.K. Datye, Hydrothermally stable heterogeneous catalysts for conversion of biorenewables [J]. Green chemistry, 2014. 16(11): 4627-4643. [9]. Qin, L Z, Song M J, Chen C L, Aqueous-phase deoxygenation of glycerol to 1,3-propanediol over Pt/WO3/ZrO2 catalysts in a fixed-bed reactor [J]. Green Chemistry, 2010. 12(8): 1466. [10].Tadahiro Kurosaka, Hideyuki Maruyama , Ikuya Naribayashi,et al ,Production of 1,3-propanediol by hydrogenolysis of glycerol catalyzed by Pt/WO3/ZrO2 [J], Catalysis Communications, 2008. 9(6): 1360-1363.

3. 毕业设计（论文）进程安排

2019.03.01-2019.04.02 1、检索和阅读相关文献； 2、学习pt/mgo/wo3-zro2催化剂的制备方法； 3、完成开题报告及指定英文文献的翻译工作。

2019.04.03-2019.05.15 1、完成pt/mgo/wo3-zro2催化剂的制备； 2、学会使用固定床； 3、完成pt/mgo/wo3-zro2催化剂催化甘油加氢制1,3-丙二醇的性能测定和液相色谱对反应液的分析； 4、运用程序升温吸附仪测定催化剂表面性质。

2019.05.16-2019.06.13 撰写毕业论文，准备论文答辩。