氧化钴基双功能纳米反应器及其在燃料降解中的应用研究任务书
2020-04-26 12:48:53
1. 毕业设计(论文)的内容和要求
利用双溶剂法将金属源送入介孔SBA-15得孔道当中,在通过高温煅烧得方法,将金属盐分解形成金属氧化物,最终达到,金属氧化物高度分散于介孔分子筛表面得状态,之后,以过硫酸盐为氧化剂,在应用到亚甲基蓝降解得反应,研究活性物种在一个限于空间内得反应行为。
2. 参考文献
[1] Kong Y, Zhang R, XU X J, et al. Synthesis and Characterization of V-MCM41 with High Vanadium Content [J]. Chinese J Inorg Chem, 2008, (24):1124-1127. [2] Wang Y, Zhang Q H, Ohishi Y, et al. Synthesis of V-MCM-41 by Template-Ion Exchange Method and Its Catalytic Properties in Propane Oxidative Dehydrogenation[J]. Catal Lett. 2001, 72 (3-4):215~219. [3] Huo Q, Margolese D I, Ciesla U, et al. Organization of organic molecules with inorganic molecular species into nanocomposite biphase arrays[J]. Chem Mater, 1994, 6 [4] Chen S Y, Tang C Y, Chuang W T, et al. A facile route to synthesizing functionalized mesoporous SBA-15 materials with platelet morphology and short mesochannels[J]. Chem Mater, 2008, 20 (12): 3906-3916. [5] Huo Q, Margolese D I, Ciesla U. Generalized synthesis of periodic surfactant/inorganic composite materials[J]. Nature, 1994, 368:317-321. [6] Liu X, Tian B, Yu C, et al. Room-Temperature Synthesis in Acidic Media of Large-Pore Three-Dimensional Bicontinuous Mesoporous Silica with Ia3d Symmetry[J]. Angew. Chem .Int. Edit. 2010, 41 (20): 3876~3878. [7] Nie D X, Liang Y, Zhou, T S, et al. FDU-15-Pt Composites with Different Pt Loading and Their Electrocatalytic Reduction to Ultratrace Nitroaromatic Compounds[J]. Int J Environ An Ch. 2012, 7(92): 832~843. [8] Tozuka Y, Wongmekiat A , Kimura K, et al. Effect of Pore Size of FSM-16 on The Entrapment of Flurbiprofen in Mesoporous Structures[J]. Chem Pharm Bull.2005,53(8): 974~977. [9] Jin D F, Hu G B, Jin H X, et al. Synthesis of Sulfated Zirconia by Grafting on Mesoporous SBA-15 by Sol-Gel Method[J]. Rare Metal Mat Eng , 2012, 41(53): 379~382.
3. 毕业设计(论文)进程安排
2019-03-2#8212;03-10查阅国内外有关文献,拟订实验方案。
2019-03-10#8212;03-22 翻译外文文献,并撰写文献综述。
2019-03-23#8212;04-8 按照拟定的实验方案依次进行实验。