1. 毕业设计（论文）的内容和要求

内容：制备MFe2O4磁性纳米颗粒，通过调控前驱体来调控M金属的类别；之后探讨不同的磁性颗粒对染料的芬顿降解性能。

要求：熟练掌握溶剂热法的原理、操作流程；了解材料表征时使用到的大型仪器设备。

2. 参考文献

[1] P. Yuan, X. Mei, B.X. Shen, F.J. Lu, W.J. Zhou, M. Si, S. Chakraborty, Oxidation of NO by in situ Fenton reaction system with dual ions as reagents, Chem. Eng. J. 351 (2018) 660-667. [2] F. Sopaj, N. Oturan, J. Pinson, F. Podvorica, M.A. Oturan, Effect of the anode materials on the efficiency of the electro-Fenton process for the mineralization of the antibiotic sulfamethazine, Appl. Catal. B-Environ. 199 (2016) 331-341. [3] X.W. Zhang, J.L. Fu, Y. Zhang, L.C. Lei, A nitrogen functionalized carbon nanotube cathode for highly efficient electrocatalytic generation of H2O2 in Electro-Fenton system, Sep. Purif. Technol. 64 (2008) 116-123. [4] X.C. Liu, Y.Y. Zhou, J.C. Zhang, L. Luo, Y. Yang, H.L. Huang, H. Peng, L. Tang, Y. Mu, Insight into electro-Fenton and photo-Fenton for the degradation of antibiotics: Mechanism study and research gaps, Chem. Eng. J. 347 (2018) 379-397. [5] W.L. Yang, M.H. Zhou, L. Liang, Highly efficient in-situ metal-free electrochemical advanced oxidation process using graphite felt modified with N-doped graphene, Chem. Eng. J. 338 (2018) 700-708. [6] O. Garcia-Rodriguez, Y.Y. Lee, H. Olvera-Vargas, F.X. Deng, Z.X. Wang, O. Lefebvre, Mineralization of electronic wastewater by electro-Fenton with an enhanced graphene-based gas diffusion cathode, Electrochim. Acta. 276 (2018) 12-20. [7] G.S. Xia, Y.H. Lu, H.B Xu, Electrogeneration of hydrogen peroxide for electro-Fenton via oxygen reduction using polyacrylonitrile-based carbon fiber brush cathode, Electrochim. Acta. 158 (2015) 390-396. [8] E. Brillas, I. Sire#769;s, M.A. Oturan, Electro-Fenton Process and related electrochemical technologies based on Fenton#8217;s reaction chemistry, Chem. Rev. 109 (2009) 6570-6631. [9] L.L. Cui, P.P. Ding, M. Zhou, W.H. Jing, Energy efficiency improvement on in situ generating H2O2 in a double-compartment ceramic membrane flow reactor using cerium oxide modified graphite felt cathode, Chem. Eng. J. 330 (2017) 1316-1325. [10] P.P. Ding, L.L. Cui, D. Li, W.H. Jing, An innovative dual-compartment flow reactor coupled with a gas diffusion electrode for in-situ generating H2O2. [11] C. Zhang, L. Zhou, J. Yang, X.M. Yu, Y.H. Jiang, M.H. Zhou, Nanoscale zero-valent iron/AC as heterogeneous Fenton catalysts in three-dimensional electrode system, Environ. Sci. Pollut. R. 21 (2014) 8398-8405. [12] C.C. Lin, S.T. Hsu, Performance of nZVI/H2O2 process in degrading polyvinyl alcohol in aqueous solutions, Sep. Purif. Technol. 203 (2018) 111-116. [13] J.M. Deng, H.R. Dong, C. Zhang, Z. Jiang, Y.J. Cheng, K.J. Hou, L.H. Zhang, C.Z. Fan, Nanoscale zero-valent iron/biochar composite as an activator for Fenton-like removal of sulfamethazine, Sep. Purif. Technol. 202 (2018) 130-137. [14] T.L.P. Dantas, V.P. Mendon#231;a, H.J. Jos#233;, A.E. Rodrigues, R.F.P.M. Moreira, Treatment of textile wastewater by heterogeneous Fenton process using a new composite Fe2O3/carbon, Chem. Eng. J. 118 (2006) 77-82. [15] G.K. Zhang, Y.Y. Gao, Y.L. Zhang, Y.D. Guo, Fe2O3-pillared rectorite as an efficient and stable Fenton-like heterogeneous catalyst for photodegradation of organic contaminants, Environ. Sci. Technol, 44 (2010) 6384-6389. [16] M.A. Voinov, J.O.S. Paga#769;n, E. Morrison, T.I. Smirnova, A.I. Smirnov, Surface-mediated production of hydroxyl radicals as a mechanism of iron oxide nanoparticle biotoxicity, J. Am. Chem. Soc, 133 (2011) 35-41. [17] G.B. Ortiz De La Plata, O.M. Alfano, A.E. Cassano, Decomposition of 2-chlorophenol employing goethite as Fenton catalyst II: Reaction kinetics of the heterogeneous Fenton and photo-Fenton mechanisms, Appl. Catal. B-Environ. 95 (2010) 14-25.

3. 毕业设计（论文）进程安排

2018.2-2018.3 查阅文献，了解课题研究意义及国内外研究进展。

2018.3-2018.5 制备材料并进行表征及性能测试实验。

2018.5-2018.6 论文撰写与修改。