中空纤维负载型硼掺杂DDR分子筛膜的制备与分离应用任务书
2020-04-26 12:49:08
1. 毕业设计(论文)的内容和要求
研究内容: 研究中空纤维B-DDR分子筛膜对于H2/CO2体系的分离,考察高温及低温、不同压力下以及不同H2摩尔分率下的分离性能。
基本要求: 1、查阅相关文献,具备英文文献阅读、整理和归纳的能力; 2、熟悉分子筛膜气体渗透与分离的基本原理; 3、掌握实验数据处理分析能力,学会Origin制图; 4、规范书写毕业论文,认真准备答辩ppt。
2. 参考文献
[1] Tomita T, Nakayama K, Sakai H. Gas separation characteristics of DDR type zeolite membrane [J]. Microporous Mesoporous Mater., 2004, 68(1-3): 71-75. [2] Gies H. Studies on clathrasils:Ⅶ. A new clathrate compound of silica: synthesis, crystallographic and thermal properties [J]. J. Inclu. Phenom., 1984, 2: 275-278. [3] M.J. Den Exter J C J, H. Van Bekkum. Separation of permanent gases on the all-silica 8-ring clathrasil DD3R [J]. Stud. Surf. Sci. Catal., 1994, 84: 1159-1166. [4] Gascon J, Blom W, Van Miltenburg A, et al. Accelerated synthesis of all-silica DD3R and its performance in the separation of propylene/propane mixtures [J]. Microporous Mesoporous Mater., 2008, 115(3): 585-593. [5] Zheng F, Jing W, Gu X, et al. Rapid synthesis of pure DD3R zeolite using ball-milled Sigma-1 seeds under static conditions [J]. J. Mater. Sci., 2013, 48(18): 6286-6292. [6] Zheng F, Jing W, Gu X, et al. Rapid synthesis of pure DD3R zeolite using ball-milled Sigma-1 seeds under static conditions [J]. Journal of Materials Science, 2013, 48(18):6286-6292. [7] Taramasso, M. Perego, G. Proceedings of the Fifth International conference on Zeolites, 40-49, London, 1980. [8] Tuan V A, Noble R D, Falconer J L. Boron-substituted ZSM-5 membranes: Preparation and separation performance [J]. AIChE Journal, 2000, 46(6):1201-1208. [9] Bowen T C, Kalipcilar H, Falconer J L, et al. Pervaporation of Organic/Water Mixtures Through B-ZSM-5 Zeolite Membranes on Monolith Supports [J]. Journal of Membrane Science, 2003, 215(1):235-247. [10] Kalipcilar H, Gade S K, Noble R D, et al. Synthesis and separation properties of B-ZSM-5 zeolite membranes on monolith supports [J]. Journal of Membrane Science, 2002, 210(1):113-127. [11] Victor Sebastian, Kumakiri I, Bredesen R, et al. Zeolite membrane for CO2 removal: Operating at high pressure [J]. Journal of Membrane Science, 2007, 292(1-2):92-97. [12] Mihalyi R M, Patis A, Nikolakis V, et al. [B] MFI membrane: Synthesis, physico-chemical properties and catalytic behavior in the double-bond isomerization of 1-butene [J]. Separation Purification Technology, 2013, 118(43):135-143. [13] Liu R, Young S, Dangwal S, et al. Boron substituted MFI-type zeolite-coated mesh for oil-water separation [J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2018, 550:108-114. [14] Gies H . Synthesis, Crystallographic, and Thermal Properties of a NEW Porous Silica [J]. Journal of Inclusion Phenomena, 1987, 5(2):283-287.
3. 毕业设计(论文)进程安排
2月-3月 阅读相关文献,完成外文翻译,文献综述等; 3月-5月 进行膜合成气体分离实验及数据整理。
5月-6月 撰写本科毕业论文、答辩。