1. 毕业设计（论文）的内容和要求

1#12289;#26597;#38405;#26377;#20851;ZIF-8#12289;#28151;#21512;#22522;#36136;#33180;#20197;#21450;#25530;#26434;#31890;#23376;#30340;#30456;#20851;#25991;#29486;#65292;#24324;#28165;#26970;#35838;#39064;#30340;#30740;#31350;#30446;#30340;#21644;#24847;#20041;#65292;#25484;#25569;#35838;#39064;#30340;#30740;#31350;#37325;#28857;#65292;#31579;#36873;#20986;#19982;#26412;#35838;#39064;#30456;#20851;#24615;#39640;#30340;#25991;#29486;#12290;#21516;#26102;#38405;#35835;#35838;#39064;#30340;#30456;#20851;#22806;#25991;#25991;#29486;#65292;#36827;#34892;#24635;#32467;#24402;#32435;#65292;#24182;#35774;#35745;#23454;#39564;#26041;#26696;#65292;#21046;#23450;#23454;#39564;#35745;#21010;#12290; 2#12289;#29087;#24713;#23454;#39564;#20202;#22120;#30340;#27491;#30830;#20351;#29992;#65292;#25552;#39640;#23454;#39564;#25805;#20316;#25216;#33021;#65292;#21512;#29702;#35268;#21010;#23454;#39564;#36827;#31243;#12290; 3#12289;#26412;#30528;#24576;#30097;#30340;#31934;#31070;#65292;#22521;#20859;#20005;#35880;#30340;#31185;#23398;#24577;#24230;#65292;#20998;#26512;#23454;#39564;#21407;#29702;#65292;#23545;#23454;#39564;#36807;#31243;#20013;#36935;#21040;#22256;#38590;#33021;#29420;#31435;#35299;#20915;#65292;#23545;#23454;#39564;#36335;#32447;#25552;#20986;#33258;#24049;#30340;#35265;#35299;#12290; 4#12289;#29087;#24713;#27605;#19994;#35770;#25991;#30340;#25776;#20889;#35268;#33539;#65292;#36890;#36807;#25776;#20889;#35770;#25991;#65292;#38203;#28860;#33258;#24049;#30340;#36923;#36753;#24605;#32500;#21644;#35821;#35328;#32452;#32455;#33021;#21147;#12290;

2. 参考文献

[1] T. Rodenas, M. van Dalen, E. Garcia-Perez, P. Serra-Crespo, B. Zornoza, F. Kapteijn, J. Gascon, Visualizing MOF mixed matrix membranes at the nanoscale: towards structure-performance relationships in CO2/CH4 separation over NH2-MIL-53(Al)@ PI, Adv. Funct. Mater. 24 (2014) 249?56. [2] B. Seoane, J. Coronas, I. Gascon, M.E. Benavides, O. Karvan, J. Caro, F. Kapteijn, J. Gascon, Metal-organic framework based mixed matrix membranes: a solution for highly efficient CO2 capture? Chem. Soc. Rev. 44 (2015) 2421?454. [3] G.P. Liu, V. Chernikova, Y. Liu, K. Zhang, Y. Belmabkhout, O. Shekhah, C. Zhang, S.L. Yi, M. Eddaoudi, W.J. Koros, Mixed matrix formulations with MOF molecular sieving for key energy-intensive separations, Nat. Mater. 17 (2018) 283?89. [4] L.M. Robeson, The upper bound revisited, J. Membr. Sci. 320 (2008) 390?00. [5] H.B. Park, J. Kamcev, L.M. Robeson, M. Elimelech, B.D. Freeman, Maximizing the right stuff: the trade-off between membrane permeability and selectivity, Science 356 (2017) 1137. [6] J.E. Bachman, J.R. Long, Plasticization-resistant Ni2(dobdc)/polyimide composite membranes for the removal of CO2 from natural gas, Energy Environ. Sci. 9 (2016) 2031?036. [7] H. An, S. Park, H.T. Kwon, H.K. Jeong, J.S. Lee, A new superior competitor for exceptional propylene/propane separations: ZIF-67 containing mixed matrix membranes, J. Membr. Sci. 526 (2017) 367?76. [8] M. Galizia, W.S. Chi, Z.P. Smith, T.C. Merkel, R.W. Baker, B.D. Freeman, 50th anniversary perspective: polymers and mixed matrix membranes for gas and vapor separation: a review and prospective opportunities, Macromolecules 50 (2017) 7809?843. [9] T.S. Chung, L.Y. Jiang, Y. Li, S. Kulprathipanja, Mixed matrix membranes (MMMs) comprising organic polymers with dispersed inorganic fillers for gas separation, Prog. Polym. Sci. 32 (2007) 483?07. [10] M. Rezakazemi, A.E. Amooghin, M.M. Montazer-Rahmati, A.F. Ismail, T. Matsuura, State-of-the-art membrane based CO2 separation using mixed matrix membranes (MMMs): an overview on current status and future directions, Prog. Polym. Sci. 39 (2014) 817?61. [11] J. Dechnik, J. Gascon, C.J. Doonan, C. Janiak, C.J. Sumby, Mixed-matrix membranes, Angew. Chem. Int. Ed. 56 (2017) 9292?310. [12] G.X. Dong, H.Y. Li, V.K. Chen, Challenges and opportunities for mixed-matrix membranes for gas separation, J. Mater. Chem. A 1 (2013) 4610?630. [13] P.S. Goh, A.F. Ismail, S.M. Sanip, B.C. Ng, M. Aziz, Recent advances of inorganic fillers in mixed matrix membrane for gas separation, Sep. Purif. Technol. 81 (2011) 243?64. [14] Z.G. Wang, D. Wang, S.X. Zhang, L. Hu, J. Jin, Interfacial design of mixed matrix membranes for improved gas separation performance, Adv. Mater. 28 (2016) 3399?405. [15] L. Xiang, L.Q. Sheng, C.Q. Wang, L.X. Zhang, Y.C. Pan, Y.S. Li, Amino-functionalized ZIF-7 nanocrystals: improved intrinsic separation ability and interfacial compatibility in mixed-matrix membranes for CO2/CH4 separation, Adv. Mater. 29 (2017) 1606999. [16] P.D. Sutrisna, J.W. Hou, H.Y. Li, Y.T. Zhang, V. Chen, Improved operational stability of Pebax-based gas separation membranes with ZIF-8: a comparative study of flat sheet and composite hollow fibre membranes, J. Membr. Sci. 524 (2017) 266?79. [17] M.S. Denny, J.C. Moreton, L. Benz, S.M. Cohen, Metal-organic frameworks for membrane-based separations, Nat. Rev. Mater. 1 (2016) 16078. [18] J. Yu, C.Q. Wang, L. Xiang, Y.Z. Xu, Y.C. Pan, Enhanced C3H6/C3H8 separation performance in poly(vinyl acetate) membrane blended with ZIF-8 nanocrystals, Chem. Eng. Sci. 179 (2018) 1?2. [19] S. Japip, H. Wang, Y.C. Xiao, T.S. Chung, Highly permeable zeolitic imidazolate framework (ZIF)#8722;71 nano-particles enhanced polyimide membranes for gas separation, J. Membr. Sci. 467 (2014) 162?74. [20] M. Askari, T.S. Chung, Natural gas purification and olefin/paraffin separation using thermal cross-linkable co-polyimide/ZIF-8 mixed matrix membranes, J. Membr. Sci. 444 (2013) 173?83. [21] T.H. Bae, J.S. Lee, W.L. Qiu, W.J. Koros, C.W. Jones, S. Nair, A high-performance gas-separation membrane containing submicrometer-sized metal-organic framework crystals, Angew. Chem. Int. Ed. 49 (2010) 9863?866. [22] J.E. Bachman, Z.P. Smith, T. Li, T. Xu, J.R. Long, Enhanced ethylene separation and plasticization resistance in polymer membranes incorporating metal-organic framework nanocrystals, Nat. Mater. 15 (2016) 845?49. [23] A. Cadiau, K. Adil, P.M. Bhatt, Y. Belmabkhout, M. Eddaoudi, A metal-organic framework-based splitter for separating propylene from propane, Science 353 (2015) 137?40. [24] P.M. Bhatt, Y. Belmabkhout, A. Cadiau, K. Adil, O. Shekhah, A. Shkurenko, L.J. Barbour, M. Eddaoudi, A fine-tuned fluorinated MOF addresses the needs for trace CO2 removal and air capture using physisorption, J. Am. Chem. Soc. 138 (2016) 9301?307. [25] S. Japip, K.S. Liao, Y.C. Xiao, T.S. Chung, Enhancement of molecular-sieving properties by constructing surface nano-metric layer via vapor cross-linking, J. Membr. Sci. 497 (2016) 248?58. [26] L. Xiang, Y.C. Pan, G.F. Zeng, J.L. Jiang, J. Chen, C.Q. Wang, Preparation of poly (ether-block-amide)/attapulgite mixed matrix membranes for CO2/N2 separation, J. Membr. Sci. 500 (2016) 66?5. [27] L. Chen, L.L. Yan, Q. Li, C.F. Wang, S. Chen, Controllable synthesis of new polymerizable macrosurfactants via CCTP and RAFT techniques and investigation of their performance in emulsion polymerization, Langmuir 26 (2010) 1724?733. [28] Z.B. Bao, L.A. Yu, Q.L. Ren, X.Y. Lu, S.G. Deng, Adsorption of CO2 and CH4 on a magnesium-based metal organic framework, J. Colloid Interf. Sci. 353 (2011) 549?56. [29] V.I. Bondar, B.D. Freeman, I. Pinnau, Gas sorption and characterization of poly (ether-b-amide) segmented block copolymers, J. Polym. Sci. Pol. Phys. 37 (1999) 2463?475. [30] T.X. Yang, T.S. Chung, Room-temperature synthesis of ZIF-90 nanocrystals and the derived nano-composite membranes for hydrogen separation, J. Mater. Chem. A 1 (2013) 6081?090. [31] L. Xiang, Y.C. Pan, J.L. Jiang, Y. Chen, J. Chen, L.X. Zhang, C.Q. Wang, Thin poly (ether-block-amide)/attapulgite composite membranes with improved CO2 permeance and selectivity for CO2/N2 and CO2/CH4, Chem. Eng. Sci. 160 (2017) 236?44. [32] S. Kelman, H.Q. Lin, E.S. Sanders, B.D. Freeman, CO2/C2H6 separation using solubility selective membranes, J. Membr. Sci. 305 (2007) 57?8. [33] A. Car, C. Stropnik, W. Yave, K.V. Peinemann, Pebax?polyethylene glycol blend thin film composite membranes for CO2 separation: performance with mixed gases, Sep. Purif. Technol. 62 (2008) 110?17. [34] M. Sindoro, A.Y. Jee, S. Granick, Shape-selected colloidal MOF crystals for aqueous use, Chem. Commun. 49 (2013) 9576?578. [35] M.Q. Fang, C.L. Wu, Z.J. Yang, T. Wang, Y. Xia, J.D. Li, ZIF-8/PDMS mixed matrix membranes for propane/nitrogen mixture separation: experimental result and permeation model validation, J. Membr. Sci. 474 (2015) 103?13. [36] K. Adil, P.M. Bhatt, Y. Belmabkhout, S.M.T. Abtab, H. Jiang, A.H. Assen, A. Mallick, A. Cadiau, J. Aqil, M. Eddaoudi, Valuing metal-organic frameworks for postcombustion carbon capture: a benchmark study for evaluating physical adsorbents, Adv. Mater. 29 (2017) 1702953. [37] X.F. Wu, M.N. Shahrak, B. Yuan, S.G. Deng, Synthesis and characterization of zeolitic imidazolate framework ZIF-7 for CO2 and CH4 separation, Microporous Mesoporous Mater. 190 (2014) 189?96. [38] W.H. Lin, R.H. Vora, T.S. Chung, Gas transport properties of 6FDA-durene/1,4- phenylenediamine (pPDA) copolyimides, J. Polym. Sci. Pol. Phys. 38 (2000) 2703?713. [39] N. Jusoh, Y.F. Yeong, K.K. Lau, A.M. Shariff, Enhanced gas separation performance using mixed matrix membranes containing zeolite T and 6FDA-durene polyimide, J. K. Chen et al. Journal of Membrane Science 563 (2018) 360?70Membr. Sci. 525 (2017) 175?86. [40] B. Ghalei, K. Sakurai, Y. Kinoshita, K. Wakimoto, A.P. Isfahani, Q.L. Song, K. Doitomi, S. Furukawa, H. Hirao, H. Kusuda, S. Kitagawa, E. Sivaniah, Enhanced selectivity in mixed matrix membranes for CO2 capture through efficient dispersion of amine-functionalized MOF nanoparticles, Nat. Energy 2 (2017) 17086. [41] N.C. Su, D.T. Sun, C.M. Beavers, D.K. Britt, W.L. Queen, J.J. Urban, Enhanced permeation arising from dual transport pathways in hybrid polymer-MOF membranes, Energy Environ. Sci. 9 (2016) 922?31. [42] M.J.C. Ordonez, K.J. Balkus, J.P. Ferraris, I.H. Musselman, Molecular sieving realized with ZIF-8/Matrimid?mixed-matrix membranes, J. Membr. Sci. 361 (2010) 28?7. [43] N. Jusoh, Y.F. Yeong, W.L. Cheong, K.K. Lau, A.M. Shariff, Facile fabrication of mixed matrix membranes containing 6FDA-durene polyimide and ZIF-8 nanofillers for CO2 capture, J. Ind. Eng. Chem. 44 (2016) 164?73. [44] N. Jusoh, Y.F. Yeong, K.K. Lau, A.M. Shariff, Transport properties of mixed matrix membranes encompassing zeolitic imidazolate framework 8 (ZIF-8) nanofiller and 6FDA-durene polymer: optimization of process variables for the separation of CO2 from CH4, J. Clean. Prod. 149 (2017) 80?5. [45] V. Nafisi, M.B. Hagg, Gas separation properties of ZIF-8/6FDA-durene diamine mixed matrix membrane, Sep. Purif. Technol. 128 (2014) 31?8. [46] B.D. Freeman, Basis of permeability/selectivity tradeoff relations in polymeric gas separation membranes, Macromolecules 32 (1999) 375?80. [47] V.T. Hoang, S. Kaliaguine, Predictive models for mixed-matrix membrane performance: a review, Chem. Rev. 113 (2013) 4980?028. [48] B. Zornoza, A. Martinez-Joaristi, P. Serra-Crespo, C. Tellez, J. Coronas, J. Gascon, F. Kapteijn, Functionalized flexible MOFs as fillers in mixed matrix membranes for highly selective separation of CO2 from CH4 at elevated pressures, Chem. Commun. 47 (2011) 9522?524. [49] Y.J. Ban, Z.J. Li, Y.S. Li, Y. Peng, H. Jin, W.M. Jiao, A. Guo, P. Wang, Q.Y. Yang, C.L. Zhong, W.S. Yang, Confinement of ionic liquids in nanocages: tailoring the molecular sieving properties of ZIF-8 for membrane-based CO2 capture, Angew. Chem. Int. Ed. 54 (2015) 15483?5487.

3. 毕业设计（论文）进程安排

#36215;#35755;#26085;#26399; #35774;#35745;#65288;#35770;#25991;#65289;#21508;#38454;#27573;#24037;#20316;#20869;#23481; #22791; #27880; 1.22-3.10 #26597;#38405;#25991;#29486;#65292;#36827;#34892;#30456;#20851;#25991;#29486;#30340;#32763;#35793;#24037;#20316;,#23436;#25104;#24320;#39064;#25253;#21578;#12290; 3.11-3.31 #20102;#35299;ZIF-8#31890;#23376;#21046;#22791;#26041;#27861;#65292;#21046;#22791;#25530;#26434;2-#20057;#22522;#21674;#21777;#30340;ZIF-8#31890;#23376;#65292;#27979;#35797;ZIF-8#31890;#23376;#30340;#34920;#24449;#65288;XRD,SEM,BET,#39640;#21387;#21560;#38468;#65289;#12290; 4.1-4.21 #20102;#35299;#28151;#21512;#22522;#36136;#33180;#30340;#21046;#22791;#26041;#27861;#12290;#21046;#22791;#28151;#21512;#22522;#36136;#33180;#65292;#27979;#35797;#28151;#21512;#22522;#36136;#33180;#30340;#34920;#24449;#65288;SEM,#32418;#22806;#65292;#39640;#21387;#21560;#38468;#65292;#21452;#32452;#20998;#27668;#20307;#20998;#31163;#65289;#12290; 4.22-5.19 #27979;#35797;#25530;#26434;2-#20057;#22522;#21674;#21777;#30340;ZIF-8#19981;#21516;#32467;#26230;#24230;#28151;#21512;#22522;#36136;#33180;#23545;#19993;#28919;/#19993;#28911;#20998;#31163;#24615;#33021;#30340;#24433;#21709;#12290; 5.20-6.4 #20889;#35770;#25991;#24182;#36827;#34892;#20462;#25913;#65292;#20934;#22791;#31572;#36777;#12290;