二氧化碳选择性加氢催化剂的研究任务书
2020-04-26 12:49:28
1. 毕业设计(论文)的内容和要求
内容: 本课题毕业论文最终分为四个章节,分别为研究背景、实验表征、结果讨论和结论展望。
要求: 掌握熟练查阅中外文文献资料的方法,了解课题的研究背景以及研究意义。
文献阅读篇数至少不低于20篇,同时,翻译一篇相关的外文文献。
2. 参考文献
1. Wang L, Zhang W, Zheng X, et al. Incorporating nitrogen atoms into cobalt nanosheets as a strategy to boost catalytic activity toward CO2 hydrogenation[J]. Nature Energy, 2017, 2(11): 869#8211;876. 2. Li H, Wang L, Dai Y, et al. Synergetic interaction between neighbouring platinum monomers in CO2 hydrogenation[J]. Nature Nanotechnology, 2018, 13(5): 411#8211;417. 3. Studt F, Sharafutdinov I, Abild-Pedersen F, et al. Discovery of a Ni-Ga catalyst for carbon dioxide reduction to methanol[J]. Nature Chemistry, 2014, 6(4):320-324. 4. Kattel S, Liu P, Chen J G. Tuning Selectivity of CO2 Hydrogenation Reactions at the Metal/Oxide Interface[J]. Journal of the American Chemical Society, 2017, 139(29):9739-9754. 5. Choi E J, Lee Y H, Lee D W, et al. Hydrogenation of CO2 to methanol over Pd#8211;Cu/CeO2 catalysts[J]. Molecular Catalysis, 2017, 434: 146-153. 6. Jiang X, Koizumi N, Guo X, et al. Bimetallic Pd#8211;Cu catalysts for selective CO2 hydrogenation to methanol[J]. Applied Catalysis B: Environmental, 2015, 170-171:173-185. 7. Xu J, Su X, Liu X, et al. Methanol synthesis from CO2 and H2 over Pd/ZnO/Al2O3: Catalyst structure dependence of methanol selectivity[J]. Applied Catalysis A General, 2016, 514:51-59. 8. Xiao J, Yang J, Colton M, et al. CO2 hydrogenation to methanol on Pd-Cu bimetallic catalysts with lower metal loadings[J]. Catalysis Communications, 2019. 118:10-14. 9. Larmier K, Wei‐Chih Liao, Tada S, et al. CO2‐to‐Methanol Hydrogenation on Zirconia‐Supported Copper Nanoparticles: Reaction Intermediates and the Role of the Metal#8211;Support Interface[J]. Angewandte Chemie International Edition, 2017, 56(9):2318-2323. 10. Medford A J, Sehested J, Rossmeisl J, et al. Thermochemistry and micro-kinetic analysis of methanol synthesis on ZnO (0001)[J]. Journal of Catalysis, 2014, 309(309):397-407. 11. Chiang C L, Lin K S, Lin Y G. Preparation and Characterization of Ni5Ga3 for Methanol Formation via CO2 Hydrogenation[J]. Topics in Catalysis, 2017, 60(9-11):685-696. 12. Choi E J, Lee Y H, Lee D W, et al. Hydrogenation of CO2 to methanol over Pd#8211;Cu/CeO2 catalysts[J]. Molecular Catalysis, 2017, 434:146-153. 13. Ouyang B, Tan W, Liu B. Morphology effect of nanostructure ceria on the Cu/CeO2 catalysts for synthesis of methanol from CO2, hydrogenation[J]. Catalysis Communications, 2017, 95:36-39. 14. Vidal A B, Feria L, Evans J, et al. CO2 Activation and Methanol Synthesis on Novel Au/TiC and Cu/TiC Catalysts[J]. Journal of Physical Chemistry Letters, 2012, 3(16):2275-2280. 15. Qingqing T, Zhisheng S, Dongfang W. CO2 Hydrogenation to Methanol over a Highly Active Cu-Ni/CeO2-Nanotube Catalyst[J]. Industrial Engineering Chemistry Research, 2018, 57(31):10148-10158. 16. Vogt C, Groeneveld E, Kamsma G, et al. Unravelling structure sensitivity in CO2 hydrogenation over nickel[J]. 2018, 1(2):127-134. 17. Nie X, Jiang X, Wang H, et al. Mechanistic Understanding of Alloy Effect and Water Promotion for Pd-Cu Bimetallic Catalysts in CO2 Hydrogenation to Methanol[J]. ACS Catalysis, 2018, 8(6):4873-4892. 18. Saeidi S, Amin N A S, Rahimpour M R. Hydrogenation of CO2 to value-added products#8212;A review and potential future developments[J]. Journal of CO2 Utilization, 2014, 5. 19. Vourros A, Garagounis I, Kyriakou V, et al. Carbon dioxide hydrogenation over supported Au nanoparticles: Effect of the support[J]. Journal of CO2 Utilization, 2017, 19:247-256. 20. Zhao F, Gong M, Zhang Y, et al. The performance and structural study of CuNi alloy catalysts for methanol synthesis[J]. Journal of Porous Materials, 2016, 23(3):733-740.
3. 毕业设计(论文)进程安排
2019.2.1-2019.2.15 查阅资料,学习相关理论知识,熟悉研究 方向。
2019.2.16-2019.2.28 在学习一定理论知识的基础上,了解所用 实验仪器的相关操作,进行安全性实验教 育学习。
2019.3.1-2019.3.20 正式开始实验部分,并完成开题报告及其 相关部分。