氨的高温可逆吸附材料研究任务书
2020-04-26 12:49:34
1. 毕业设计(论文)的内容和要求
本课题要求在查阅中外文文献的基础上,了解明白氨气吸附的基本原理,熟悉并掌握氨气吸附剂的性能计算的相关流程。
课题要求: 1.学会采用各种文献检索手段对特定课题进行检索的方法,培养阅读中外文献资料的能力。
2.培养综合运用所学专业知识分析、解决实际问题的能力。
2. 参考文献
[1] Aoki, T.; Ichikawa, T.; Miyaoka, H.; Kojima, Y. Thermodynamics on Ammonia Absorption of Metal Halides and Borohydrides. J.Phys. Chem. C 2014, 118 (32), 18412#8722;18416.. [2] 杨国华, 黄统琳, 姚忠亮, 等. 吸附剂的应用研究现状和进展[J]. 化学工程与装备, 2009, 6: 84-88. [3] Malmali M, Le G, Hendrickson J, et al. Better absorbents for ammonia separation[J]. ACS Sustainable Chemistry Engineering, 2018, 6(5): 6536-6546. [4] Aoki T, Miyaoka H, Inokawa H, et al. Activation on ammonia absorbing reaction for magnesium chloride[J]. The Journal of Physical Chemistry C, 2015, 119(47): 26296-26302. [5] Sharonov V E, Aristov Y I. Ammonia adsorption by MgCl 2, CaCl 2 and BaCl 2 confined to porous alumina: the fixed bed adsorber[J]. Reaction Kinetics and Catalysis Letters, 2005, 85(1): 183-188. [6] 傅成诚, 梅凡民, 周亮, 等. 改性活性炭对氨气吸附性能的研究[J]. 紡織高校基礎科學學報, 2009, 22(3): 386-389. [7] Wagner K, Malmali M, Smith C, et al. Column absorption for reproducible cyclic separation in small scale ammonia synthesis[J]. AIChE Journal, 2017, 63(7): 3058-3068. [8] Saha D, Deng S. Characteristics of ammonia adsorption on activated alumina[J]. Journal of Chemical Engineering Data, 2010, 55(12): 5587-5593. [9] Rodrigues C C, de Moraes Jr D, Da Nobrega S W, et al. Ammonia adsorption in a fixed bed of activated carbon[J]. Bioresource Technology, 2007, 98(4): 886-891. [10] Himstedt H H, Huberty M S, McCormick A V, et al. Ammonia synthesis enhanced by magnesium chloride absorption[J]. AIChE Journal, 2015, 61(4): 1364-1371. [11] Huberty M S, Wagner A L, McCormick A, et al. Ammonia absorption at haber process conditions[J]. AIChE Journal, 2012, 58(11): 3526-3532. [12] Jacobsen H S, Hansen H A, Andreasen J W, et al. Nanoscale structural characterization of Mg (NH3) 6Cl2 during NH3 desorption: An in situ small angle X-ray scattering study[J]. Chemical physics letters, 2007, 441(4-6): 255-260. [13] Ammitzb#248;ll A L, Lysgaard S, Klukowska A, et al. Surface adsorption in strontium chloride ammines[J]. The Journal of chemical physics, 2013, 138(16): 164701. [14] 盛丽丽, 唐颖, 尹魏能, 等. 改性活性炭对氨气吸附性能研究[J]. 林产化学与工业, 2010, 30(5): 35-39. [15] 何余生, 李忠, 奚红霞, 等. 气固吸附等温线的研究进展[D]. , 2004.
3. 毕业设计(论文)进程安排
2019.2-2019.3 初步了解有关课题的背景知识; 2019.3-2019.4 阅读与氨气有关的论文及文献,并且以专题形式学习氨气吸附的相关流程并熟悉实验装置; 2019.4-2019.5 在实验的基础上对吸附剂及其性能进行计算; 2019.5-2019.6 根据前面所做的计算和图形的绘制,完成毕业论文的书写;准备毕业论文答辩。