磷硼烷自燃型离子液体的合成研究任务书
2020-04-26 12:54:29
1. 毕业设计(论文)的内容和要求
随着绿色化学的发展和科学技术的不断进步,环保问题越来越成为当今社会人们所关注的一个热门问题。
目前,我国航天事业正处于蓬勃发展阶段,火箭推进剂使用量巨大,然而在一些传统的火箭推进系统中,剧毒、强致癌、高挥发性的肼类衍生物燃料仍然是液体双组元推进剂的主要燃料选择,给环境保护和绿色化学的发展带来了极大阻力,若处理不适当,会造成极大的大气,水体,土壤污染,与如今以人为本,绿色清洁的观念相悖。
因此,对航空航天事业而言,新型绿色低毒推进剂的研究是目前一个十分重要课题。
2. 参考文献
[1] 刘志娟,郭斌. 肼类火箭推进剂气体检测技术[J]. 低温与特气,2007,02:37-42. [2] 梁彦,张弛,郑宏建. 火箭推进剂的发展特点分析[J]. 飞航导弹,2003,07:47-50 55. [3] 郑宏建. 液体火箭推进剂贮存技术[J]. 上海航天,2001,05:61-64. [4] 王强,梁洪泽,包伟良. 功能化离子液体的制备及其在合成中的应用[J]. 应用化学,2007,02:117-123. [5] 张晓春,张锁江,左勇,赵国英,张香平. 离子液体的制备及应用[J]. 化学进展,2010,07:1499-1508. [6] 王风彦,邵光杰. 离子液体应用研究进展[J]. 化学试剂,2009,01:25-30. [7] 孙甜甜. 叠氮含能燃料的合成及物性研究[D].浙江大学,2013. [8] 田均均,张庆华. 含能离子液体#8212;#8212;新型离子炸药和绿色推进剂燃料[J]. 含能材料,2014,05:580-581. [9] 黄海丰,孟子晖,周智明,高海翔,章军,吴玉凯. 含能盐和含能离子液体[J]. 化学进展,2009,01:152-163. [10] 张光全. 离子液体在含能材料领域的应用进展[J]. 含能材料,2012,02:240-247. [11] 刘跃佳,张晓娟,宁弘历,杨海君. 咪唑类含能离子液体的合成及性能研究[J]. 有机化学,2016,05:1133-1142. [12] Huang S, Qi X, Liu T, Wang K, Zhang W, Li J, Zhang Q. 2016. Towards Safer Rocket Fuels: Hypergolic Imidazolylidene-Borane Compounds as Replacements for Hydrazine Derivatives[J]. CHEMISTRY-A EUROPEAN JOURNAL, 22(29): 10187-10193. [13] Zhang Y, Gao H, Joo Y, Shreeve J M. 2011. Ionic Liquids as Hypergolic Fuels[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 50(41): 9554-9562. [14] Liu T, Qi X, Huang S, Jiang L, Li J, Tang C, Zhang Q. 2016. Exploiting hydrophobic borohydride-rich ionic liquids as faster-igniting rocket fuels[J]. CHEMICAL COMMUNICATIONS, 52(10): 2031-2034. [15] Zhang W, Qi X, Huang S, Li J, Zhang Q. 2015. Super-base-derived hypergolic ionic fuels with remarkably improved thermal stability[J]. JOURNAL OF MATERIALS CHEMISTRY A, 3(41): 20664-20672. [16] Wang K, Zhang Y, Chand D, Parrish D A, Shreeve J M. 2012. Boronium-Cation-Based Ionic Liquids as Hypergolic Fluids[J]. CHEMISTRY-A EUROPEAN JOURNAL, 18(52): 16931-16937. [17] Schneider S, Hawkins T, Rosander M, et al. Ionic liquids as hypergolic fuels[J]. Energy Fuels, 2008, 22(4): 2871-2872. [18] Li S, Gao H, Shreeve J M. Borohydride Ionic Liquids and Borane/Ionic‐Liquid Solutions as Hypergolic Fuels with Superior Low Ignition‐Delay Times[J]. Angewandte Chemie International Edition, 2014, 53(11): 2969-2972. [19]Zhang Q, Yin P, Zhang J, et al. Cyanoborohydride‐Based Ionic Liquids as Green Aerospace Bipropellant Fuels[J]. Chemistry#8211;A European Journal, 2014, 20(23): 6909-6914. [20]Chand D, Zhang J, Shreeve J M. Borohydride Ionic Liquids as Hypergolic Fuels: A Quest for Improved Stability[J]. Chemistry#8211;A European Journal, 2015, 21(38): 13297-13301. [21] Fareghi-Alamdari R, Ghorbani-Zamani F, Zekri N. Synthesis and hypergolic activity evaluation of some new ammonium-imidazolium based ionic liquids[J]. RSC Advances, 2016, 6(31): 26386-26391. [22] Liu T, Qi J, Wang B, et al. Rational Design and Facile Synthesis of Boranophosphate Ionic Liquids as Hypergolic Rocket Fuels[J]. Chemistry#8211;A European Journal, 2018. [23] Huang S, Zhang W, Liu T, et al. Towards N‐Alkylimidazole Borane‐based Hypergolic Fuels[J]. Chemistry#8211;An Asian Journal, 2016, 11(24): 3528-3533. [24] Li X, Lu T, Nan J, et al. Hydrophobic Hydrolytic‐Stable N‐Alkylimidazole‐Cyanoborane Complexes as Ultrafast‐Igniting Hypergolic Fuels[J]. ChemistrySelect, 2018, 3(9): 2548-2552.
3. 毕业设计(论文)进程安排
2019.1.8-2019.3.13 查阅文献,确定实验方法和实验条件,完成外文文献翻译和开题报告。
2019.3.14-2019.4.15 利用课题组已有基础,制备各组咪唑类含能离子液体。
2019.4.16-2019.5.15 对各组咪唑类含能离子液体进行表征,确定各项参数,选取最优组别。