基于ZIF-8的一价铜复合材料的制备及性能研究任务书
2020-04-26 12:54:39
1. 毕业设计(论文)的内容和要求
(1) 结合课题的研究,加深对基本理论、基本知识以及课题背景知识的理解。
(2) 能尽快进入课题研究领域展开思考,加强分析问题解决问题的能力。
(3) 学会检索中外文文献,阅读文献并归纳总结,为以后的学习或工作提供条件。
2. 参考文献
[1] Graetz, J., New Approaches to Hydrogen Storage. Chem. Soc. Rev. 2009, 38 (1), 73-82. [2] Rosi, N. L.; Eckert, J.; Eddaoudi, M.; Vodak, D. T.; Kim, J.; O'Keeffe, M.; Yaghi, O. M., Hydrogen Storage in Microporous Metal-Organic Frameworks. Science 2003, 300 (5622), 1127-1129. [3] Yuan, S.; Zou, L.; Qin, J.-S.; Li, J.; Huang, L.; Feng, L.; Wang, X.; Bosch, M.; Alsalme, A.; Cagin, T.; Zhou, H.-C., Construction of Hierarchically Porous Metal-organic Frameworks through Linker Labilization. Nat. Commun. 2017, 8 (15356), 1-10. [4] Yang, S. J.; Kim, T.; Im, J. H.; Kim, Y. S.; Lee, K.; Jung, H.; Park, C. R., MOF-Derived Hierarchically Porous Carbon with Exceptional Porosity and Hydrogen Storage Capacity. Chem. Mater. 2012, 24 (3), 464-470. [5] Qiu, L.-G.; Xu, T.; Li, Z.-Q.; Wang, W.; Wu, Y.; Jiang, X.; Tian, X.-Y.; Zhang, L.-D., Hierarchically Micro- and Mesoporous Metal-Organic Frameworks with Tunable Porosity. Angew. Chem., Int. Ed. 2008, 47 (49), 9487-9491. [6] Park, K. S.; Ni, Z.; Cote, A. P.; Choi, J. Y.; Huang, R. D.; Uribe-Romo, F. J.; Chae, H. K.; O'Keeffe, M.; Yaghi, O. M., Exceptional Chemical and Thermal Stability of Zeolitic Imidazolate Frameworks. PNAS 2006, 103 (27), 10186-10191. [7] Banerjee, R.; Phan, A.; Wang, B.; Knobler, C.; Furukawa, H.; O'Keeffe, M.; Yaghi, O. M., High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application to CO2 Capture. Science 2008, 319 (5865), 939-943. [8] H. Y. Huang; Y. Q. Li; N. Wang; S. R. Chen; C. Wang; T. L. Ma, Inorganic Chem. Commun., 2019, 101, 23-26. [9] Y. Q. Su; H. T. Xu; J. J. Wang; X. K. Luo; Z. L. Xu; K. F. Wang; W. Z. Wang, Nano Research, 2019, 12, 625-630. [10] Snurr, R. Q.; Hupp, J. T.; Nguyen, S. T., Prospects for Nanoporous Metal-Organic Materials in Advanced Separations Processes. AIChE J. 2004, 50 (6), 1090-1095. [11] Wang, B.; Cote, A. P.; Furukawa, H.; O'Keeffe, M.; Yaghi, O. M., Colossal Cages in Zeolitic Imidazolate Frameworks as Selective Carbon Dioxide Reservoirs. Nature 2008, 453 (7192), 207-211. [12] Luna-Triguero, A.; Vicent-Luna, J. M.; Gomez-Alvarez, P.; Calero, S., Olefin/Paraffin Separation in Open Metal Site Cu-BTC Metal-Organic Framework. J. Phys. Chem. C 2017, 121 (5), 3126-3132. [13] Hwang, Y. K.; Hong, D.-Y.; Chang, J.-S.; Jhung, S. H.; Seo, Y.-K.; Kim, J.; Vimont, A.; Daturi, M.; Serre, C.; Ferey, G., Amine Grafting on Coordinatively Unsaturated Metal Centers of MOFs: Consequences for Catalysis and Metal Encapsulation. Angew. Chem., Int. Ed. 2008, 47 (22), 4144-4148. [14] Corma, A.; Garcia, H.; Llabres i Xamena, F. X. L. I., Engineering Metal Organic Frameworks for Heterogeneous Catalysis. Chem. Rev. 2010, 110 (8), 4606-4655. [15] Pathan, N. B.; Rahatgaonkar, A. M.; Chorghade, M. S., Metal-Organic Framework Cu3(BTC)2(H2O)3 Catalyzed Aldol Synthesis of Pyrimidine-Chalcone Hybrids. Catal. Commun. 2011, 12 (12), 1170-1174.
3. 毕业设计(论文)进程安排
2019.2.26-2019.3.10 查阅收集文献资料,了解课题背景;并整理资料,撰写毕业论文开题报告; 2019.3.10-2019.5.1 熟悉相关仪器,准备实验药品,开始制备金属复合材料; 2019.5.1-2019.5.15 继续材料,将其应用于吸附,测试并比较其性能,并且撰写中期自查表; 2019.5.15-2019.6.1 整理并补充实验数据,为撰写论文作准备; 2019.6.1-2019.6.15 撰写论文,准备论文答辩。