1. 毕业设计（论文）的内容和要求

1. 查阅相关文献了解目前串级催化材料的研究现状，了解课题相关背景，已有成果以及存在的问题，对论文的研究方向有较深入的认识。

2. 增强分析问题解决问题的能力，培养独立思考及动手做实验的能力。

3. 了解实验仪器的具体使用方法和常规的表征方法。

2. 参考文献

[1]Wang C, An B, Lin W. Metal#8211;Organic Frameworks in Solid#8211;Gas Phase Catalysis[J]. ACS Catalysis, 2018, 9(1): 130-146. [2]Chughtai A H, Ahmad N, Younus H A, et al. Metal#8211;organic frameworks: versatile heterogeneous catalysts for efficient catalytic organic transformations[J]. Chemical Society Reviews, 2015, 44(19): 6804-6849. [3]Li Q, Tu B. Metal-organic frameworks with multi-components in order[J]. Foundations of Crystallography, 2017, 70: C842. [4]Xu C, Fang R, Luque R, et al. Functional metal#8211;organic frameworks for catalytic applications[J]. Coordination Chemistry Reviews, 2019, 388: 268-292. [5]Brunelli N A, Jones C W. Tuning acid#8211;base cooperativity to create next generation silica-supported organocatalysts[J]. Journal of catalysis, 2013, 308: 60-72. [6]Santiago-Portillo A, Blandez J F, Naval#243;n S, et al. Influence of the organic linker substituent on the catalytic activity of MIL-101 (Cr) for the oxidative coupling of benzylamines to imines[J]. Catalysis Science Technology, 2017, 7(6): 1351-1362. [7]Li B, Zhang Y, Ma D, et al. A strategy toward constructing a bifunctionalized MOF catalyst: post-synthetic modification of MOFs on organic ligands and coordinatively unsaturated metal sites[J]. Chemical Communications, 2012, 48(49): 6151-6153. [8]Chang G, Huang M, Su Y, et al. Immobilization of Ag (i) into a metal#8211;organic framework with#8211;SO 3 H sites for highly selective olefin#8211;paraffin separation at room temperature[J]. Chemical Communications, 2015, 51(14): 2859-2862. [9]Hasan Z, Choi E J, Jhung S H. Adsorption of naproxen and clofibric acid over a metal#8211;organic framework MIL-101 functionalized with acidic and basic groups[J]. Chemical engineering journal, 2013, 219: 537-544. [10]Zhou Y X, Chen Y Z, Hu Y, et al. MIL‐101‐SO3H: A Highly Efficient Broslash;nsted Acid Catalyst for Heterogeneous Alcoholysis of Epoxides under Ambient Conditions[J]. Chemistry#8211;A European Journal, 2014, 20(46): 14976-14980. [11]Wang Z, Cohen S M. Tandem modification of metal#8211;organic frameworks by a postsynthetic approach[J]. Angewandte Chemie, 2008, 120(25): 4777-4780. [12]Ahmed I, Hasan Z, Khan N A, et al. Adsorptive denitrogenation of model fuels with porous metal-organic frameworks (MOFs): Effect of acidity and basicity of MOFs[J]. Applied Catalysis B: Environmental, 2013, 129: 123-129. [13]Lu W, Yuan D, Sculley J, et al. Sulfonate-grafted porous polymer networks for preferential CO2 adsorption at low pressure[J]. Journal of the American Chemical Society, 2011, 133(45): 18126-18129. [14]Juan-Alcantilde;iz J, Gielisse R, Lago A B, et al. Towards acid MOFs#8211;catalytic performance of sulfonic acid functionalized architectures[J]. Catalysis Science Technology, 2013, 3(9): 2311-2318. [15]Li B, Leng K, Zhang Y, et al. Metal#8211;organic framework based upon the synergy of a Broslash;nsted acid framework and Lewis acid centers as a highly efficient heterogeneous catalyst for fixed-bed reactions[J]. Journal of the American Chemical Society, 2015, 137(12): 4243-4248.

3. 毕业设计（论文）进程安排

2019.2.26-2019.3.10 查阅收集文献资料，了解课题背景，完成开题报告的撰写,为实验作准备工作。

2019.3.11-2019.3.31 合成mofs材料。

2019.4.1-2019.4.15 对合成的样品进行相应的表征测试，并且撰写中期自查表 2019.4.16-2019.4.30 探索催化剂的催化性能，同时撰写毕业论文。