复合床层净化制氢动态吸附研究任务书
2020-04-26 12:57:12
1. 毕业设计(论文)的内容和要求
1.查阅相关文献了解目前净化制氢的研究现状,了解课题相关背景,已有成果以及存在的问题,对论文的研究方向有较深入的认识。
2.增强分析问题解决问题的能力,培养独立思考及动手做实验的能力。
3.了解实验仪器的具体使用方法和常规的表征方法。
2. 参考文献
[1] Ju Li. Theoretical evaluation of hydrogen storage capacity in pure carbon nanostructures. Chem. Phys., 2003,119(4):2376-2385. [2] MacDowell N., Florin N., Buchard A., et al. An overview of CO2 capture technologies. Energy Environ. Sci., 2010, 3(11): 1645-1669. [3] Evan J. G., Thomas O. B. Review of novel methods for carbon dioxide separation from flue and fuel gases. Fuel Process Technol., 2005, 86(14-15): 1423-1434. [4] Foeth F., Andersson M., Bosch H., et al. Separation of dilute CO2-CH4 mixture by adsorption on actived carbon. Sep. Sci. Technol., 1994, 29(1): 93-118. [5] D'Alessandro D. M., Smit B., Long J. R. Carbon dioxide capture: prospects for new materials. Angew. Chem. Int. Ed., 2010, 49(35): 6058-6082. [6] Walton K S, Levan M D. A novel adsorption cycle for CO2 recovery: experimental and theoretical investigations of a temperature swing compression process. Sep. Sci. Technol., 2006, 41(3): 485-500. [7] Qin J.-X., Tan P., Jiang Y., et al. Functionalization of metal-organic frameworks with cuprous sites using vapor-induced selective reduction: efficient adsorbents for deep desulfurization. Green Chem., 2016, 18(11): 3210-3215. [8] Li X.-Y., Zhang D.-Y., Liu X.-Q., et al. A tandem demetalization#8211;desilication strategy to enhance the porosity of attapulgite for adsorption and catalysis. Chem. Eng. Sci., 2016, 141, 184-194. [9] Kang Y.-H., Liu X.-D., Yan N., et al. Fabrication of isolated metal#8211;organic polyhedra in confined cavities: adsorbents/catalysts with unusual dispersity and activity. J. Am. Chem. Soc., 2016, 138(19): 6099-6102. [10] Geng J.-C., Xue D.-M., Liu X.-Q., et al. N-doped porous carbons for CO2 capture: Rational choice of N-containing polymer with high phenyl density as precursor. AIChE J., 2017, 63(5): 1648-1658. [11] Kevin Proops. Hydrogen generation and production trends[C]. American Fuel Petrochemical Manufacturers, Annual Meeting March 23-25, 2014 [12] Joao J. Alves, Gavin P. Towler. Analysis of Refinery Hydrogen Distribution Systems[J]. Industrial engineering chemistry research, 2002, 41 (23), 5759#8211;5769 [13] F. Liu, N. Zhang, Strategy of Purifier Selection and Integration in Hydrogen Networks [J]. Chemical Engineering Research and Design, 2004, 82(10), 1315#8211;1330 [14] Miller, G, Stoecker, J. Selection of a hydrogen separation process[C]. In: NPRA Annual Meeting, 1989 [15] Spillmann, R.W. Economics of gasseparation membranes[J]. Chemical Engineering Progress, 1989, 82(10),41#8211;62
3. 毕业设计(论文)进程安排
2019.2.26-2019.3.10 查阅收集文献资料,了解课题背景,完成开题报 告的撰写,为实验作准备工作。
2019.3.11-2019.3.31 筛选吸附剂,设计动态实验。
2019.4.1-2019.4.30 对吸附剂进行相应的表征测试,开展动态吸附研究,并且撰写中期自查表 2019.5.1-2019.5.30 研究不同条件下的动态吸附性能,同时撰写毕业论文。