Ce0.8Sm0.2O2-δ-Ba0.3Sr0.7Fe0.9Mo0.1O3-δ双相膜制备及氧渗透性能研究任务书
2020-05-01 08:40:18
1. 毕业设计(论文)的内容和要求
作为传统低温空气分离技术的替代技术,基于混合离子电子传导膜的氧分离技术因其较低的制氧成本而引起了广泛关注。
依据相组成的数量,混合离子电子传导氧传输材料通常可分为两种类型:单相氧传输膜材料和双相氧传输膜材料。
由于其高氧渗透性能和低成本,通式为abo3的单钙钛矿型透氧材料在过去的二十年中已经被广泛研究。
2. 参考文献
[1] S. Guo, Z. Liu, J. Zhu, X. Jiang, Z. Song, W. Jin, Highly oxygen-permeable and CO 2 -stable Ce 0.8 Sm 0.2 O 2 #8722; δ -SrCo 0.9 Nb 0.1 O 3 #8722; δ dual-phase membrane for oxygen separation, Fuel Processing Technology, 154 (2016) 19-26. [2] Y. He, L. Shi, F. Wu, W. Xie, S. Wang, D. Yan, P. Liu, M.-R. Li, J. Caro, H. Luo, A novel dual phase membrane 40 wt% Nd0.6Sr0.4CoO3#8722;δ#8211;60 wt% Ce0.9Nd0.1O2#8722;δ: design, synthesis and properties, Journal of Materials Chemistry A, 6 (2018) 84-92. [3]Zhu Xuefeng,Liu Huanying,Cong You,Yang Weishen. Novel dual-phase membranes for CO2 capture via an oxyfuel route.[J]. Chemical Communications,2011,48(2). [4]陈婷,江莞,江伟辉,刘健敏,张筱君,谢志翔.双相混合导体膜氧渗透性能改善的研究进展[J].无机材料学报,2015,30(12):1233-1242. [5]Jiawei Zhu,Guangru Zhang,Gongping Liu,Zhengkun Liu,Wanqin Jin,Nanping Xu. Perovskite Hollow Fibers with Precisely Controlled Cation Stoichiometry via One‐Step Thermal Processing[J]. Advanced Materials,2017,29(18). [6]Wei Fang,Dr. Fangyi Liang,Dr. Zhengwen Cao,Frank Steinbach,Prof. Dr. Armin Feldhoff. A Mixed Ionic and Electronic Conducting Dual‐Phase Membrane with High Oxygen Permeability[J]. Angewandte Chemie,2015,127(16). [7]Wanqin Jin,Chun Zhang,Peng Zhang,Yiqun Fan,Nanping Xu. Thermal decomposition of carbon dioxide coupled with POM in a membrane reactor[J]. AIChE Journal,2006,52(7). [8]Xuefeng Zhu,Haihui Wang,Weishen Yang. Relationship between homogeneity and oxygen permeability of composite membranes[J]. Journal of Membrane Science,2007,309(1). [9]Xuefeng Zhu,Yan Liu,You Cong,Weishen Yang. Ce 0.85 Sm 0.15 O 1.925 #8211;Sm 0.6 Sr 0.4 Al 0.3 Fe 0.7 O 3 dual-phase membranes: One-pot synthesis and stability in a CO 2 atmosphere[J]. Solid State Ionics,2013,253. [10]李春宏,仇卫华,李敬,康晓丽,鲁雄刚,李福.固相反应合成钙钛矿型氧化物Ba_(1.0)Co_(0.7)Fe_(0.2)Nb_(0.1)O_(3-δ)的机理[J].北京科技大学学报,2009,31(01):78-82 97. [11]姜红,孟烈,陈日志,金万勤,邢卫红.反应-膜分离耦合强化技术的研究进展[J].化学反应工程与工艺,2013,29(03):199-207. [12]Haihui Wang,Wei Shen Yang,You Cong,Xuefeng Zhu,Y.S. Lin. Structure and oxygen permeability of a dual-phase membrane[J]. Journal of Membrane Science,2003,224(1). [13]Xuefeng Zhu,You Cong,Weishen Yang. Oxygen permeability and structural stability of BaCe 0.15 Fe 0.85 O 3#8722; δ membranes[J]. Journal of Membrane Science,2006,283(1). [14]Qiming Li,Xuefeng Zhu,Yufeng He,Weishen Yang. Partial oxidation of methane in BaCe 0.1 Co 0.4 Fe 0.5 O 3#8722; δ membrane reactor[J]. Catalysis Today,2009,149(1). [15]Xuefeng Zhu,Weishen Yang. Critical Factors Affecting Oxygen Permeation Through Dual-phase Membranes[J]. Membrane Science and Technology,2011,14.
3. 毕业设计(论文)进程安排
18.01.11~18.02.23:查阅各种课题背景资料,完成英文文献的阅读和翻译,同时开始准备实验计划、拟定实验方案; 18.02.23~18.03.20: 完成不同组成的SDC-BSFM双相膜的制备,并进行初步表征; 18.03.20~18.05.20:完成本课题实验工作,完成相关性能测试,优化SDC-BSFM双向膜的透氧性能和稳定性; 18.05.20~18.06.10:完成本科毕业论文的撰写以及辅助材料,完成PPT,同时准备毕业答辩。