胆碱氨基酸离子液体用于CH4/CO2过程分离的热力学研究任务书
2020-05-17 21:39:21
1. 毕业设计(论文)的内容和要求
胆碱氨基酸离子液体是一类绿色的离子液体,价格低廉且原料来源广泛,通过离子交换的方法制备该种离子液体,离子液体的性质通过热重分析(TGA)、核磁共振等方法进行表征,由于离子液体的粘度高、吸收速率慢的特点,将离子液体与聚乙二醇(PEG200)混合,测定气体(CO2,N2、CH4)在离子液体中的溶解度,推导出离子液体体系的热力学性质,同时研究不同配比条件下离子液体吸收CO2的传递系数。
2. 参考文献
[1] 刘畅,陆小华.我国碳减排模式探讨#8212;#8212;CCS路线与生物甲烷路线的比较.化工学报[J], 2013,64(1):7-10 [2] Bandyopadhyay A. Amine versus ammonia absorption of CO2 as a measure of reducing GHG emission: a critical analysis[J]. Clean Technologies and Environmental Policy, 2011, 13: 269-294 [3] Yang Tao(阳涛), Bi Yin(毕崟), Guo Kaihua(郭开华). Carbon dioxide absorption in 1-aminopropyl-3-methylimidazolium bromide aqueous solutions[J]. CIESC Journal (化工学报), 2012, 63(10): 3152-3157 [4] 姜宁,李春福.天然气脱二氧化碳工艺方法综述.化学工程与装备[J],2011,7:147-150 [5] Hongqun Yang,Zhenghe Xu, Maohong Fan. Progress in carbon dioxide separation and capture: A review. Journal of Environmental Sciences, 2008,20:14#8211;27 [6] S.S. Kapdi,V.K.Vijay. Biogas scrubbing, compression and storage:perspective and prospectus in Indian context. Renewable Energy ,2005,30:1195#8211;1202 [7] Amitava Bandyopadhyay. Amine versus ammonia absorption of CO2 as a measure of Reducing GHG emission: a critical analysis. Clean Techn Environ Policy,2011,13:269#8211;294 [8] 张京亮, 赵杉林. 现代二氧化碳吸收工艺研究. 当代化工 [J],2011,40(1):88-91 [9] M. Hasib-ur-Rahman, M. Siaj. Ionic liquids for CO2 capture#8212;Development and progress, Chemical Engineering and Processing 2010,49: 313#8211;322 [10] Xiaoyong Li, Minqiang Hou. Solubility of CO2 in a Choline Chloride Urea Eutectic Mixture, J. Chem. Eng. Data ,2008, 53:548#8211;550
3. 毕业设计(论文)进程安排
2.20-3.15 文献调研 3.15-3.30 胆碱离子液体制备 3.30-4.25 热力学及动力学数据测定 4.25-5.15 实验数据分析 5.15- 毕业论文书写及准备答辩