有机聚合物材料包覆的纳米钯催化剂在Suzuki-Miyaura反应中的应用任务书
2020-05-18 21:18:27
1. 毕业设计(论文)的内容和要求
在最近的几十年里,Pd催化Suzuki-Miyaura 反应已经受到越来越多的关注,因为它能够广泛应用在农药、医药、有机中间体等有机合成反应中。由于均相催化剂在分离、重复使用和工业应用中存在一定的局限性以及异相催化剂活性不高等缺点,本论文重点研究了制备含膦配体负载到有机聚合物材料上的金属钯催化剂的制备以及纳米Pd 催化剂对Suzuki-Miyaura 反应的催化性能。
2. 参考文献
[1]. (a) v. farina, adv. synth. catal.,2004, 346, 1553; (b) h.-u. blaser, a. indolese, f.naud,u.nettekoven and a. schnyder, adv. synth. catal., 2004,346, 1583; (c) a. zapf and m. beller, chem. commun.,2005, 431; (d) k. c. nicolaou, p. g. bulger and d. sarlah,angew. chem., 2005, 117, 4516; angew. chem., int. ed.,2005, 44, 4442; (e) g. zeni and r. c. larock, chem. rev.,2006, 106, 4644; (f) j.-l. malleron, j.-c. fiaud and j.-y. legros, handbook of palladium catalyzed organic reactions: synthetic aspects and catalytic cycles, academic press, san diego, 1997; (g) j. tsuji, palladium reagents and catalysts: innovations in organic synthesis, wiley,chichester, 1995; (h) s. budagumpi, r. a. haque and a. w. salman, coord. chem. rev., 2012, 256, 1787; (i) e. a. b. kantchev, c. j. o乫brien and m. g. organ, angew.chem., int. ed., 2007, 46, 2768; (j) r. st丯urmer, angew.chem., int. ed., 1999, 33, 3307.
[2]. j.-c. hierso, m. beauperin and p. meunier, eur. j. inorg.chem., 2007, 3760.
[3]. (a) g. bringmann, r. gotz, p. a. keller, r. walter,m. r. boyd, f. lang, a. garcia, j. j. walsh, i. tellitu,k. v. bhaskar and t. r. kelly, j. org. chem., 1998, 63,1090; (b) m. vilaro, g. arsequell, g. valencia,a. ballesteros and j. barluenga, org. lett.,2008, 10, 3243;(c) j. k. liu, chem. rev., 2006, 106, 2209.
3. 毕业设计(论文)进程安排
按学校安排