1. 毕业设计（论文）的内容和要求

1. 查阅文献，阅读、整理文献资料，了解课题的背景及研究意义，掌握费托合成催化剂载体制备的基本原理，撰写开题报告； 2. 强化英文文献的阅读能力，扩充、积累该领域专业词汇，对文献重点部分能够进行翻译。

3. 要求学生阅读催化剂载体制备、表征及催化载体研究方法等书籍，熟悉载体的制备方法，为毕业论文后期进行的载体制备、表征及结果分析等奠定基础。

4. 掌握载体的常用改性方法，对试验结果进行合理的分析。

2. 参考文献

[1] 武保平,沈建等. 微孔-介孔复合分子筛HY-SBA-15 的表征及应用[J]. 燃料化学学报, 2012, 6: 732-736. [2] Sufang Chen,Jinlin Li, Yuhua Zhang, et al. Ru catalysts supported on Al#8211;SBA-15 with high aluminum content and their bifunctional catalytic performance in Fischer-Tropsch synthesis[J]. Royal Society of Chemistry, 2014, 4: 1005-1011. [3] Bo Zeng, Bo Hou, Litao Jia, et al. Fischer#8211;Tropsch synthesis over different structured catalysts: The effect of silica coating onto nanoparticles[J]. Journal of Molecular Catalysis A: Chemical, 2013, 379: 263-268. [4] 代郁，周亚松，魏强等人.铝修饰改性对SBA-15分子筛性质及催化剂性能的影响[J].燃料化学学报, 2013, 12: 1502-1506. [5] 徐燕,邢丽书,李湘萍等无外加酸体系中高温合成Al-SBA-15 [J]. 无机化学学报, 2013, 9: 1849-1855. [6] Qing-Qing Hao, Yong-Hua Zhao, Huan-Huan Yang, et al. Alumina Grafted to SBA-15 in Supercritical CO2 as a Support of Cobalt for Fischer#8722;Tropsch Synthesis[J]. energyfuels, 2012. 26: 6567-6575. [7] Yuanfeng Wei, Yongfei Li,et al. A facile route foro ne-pot synthesis of short-channeled bimetallic Zr#8211;Al#8211;SBA-15[J]. Materials Letters, 2015, 141: 145#8211;148 [8] 吴淑杰, 黄家辉, 吴通好等人, Al-SBA-15介孔分子筛的合成、表征及其在 苯酚叔丁基化反应中的催化性能[J]. 催化学报, 2013, 1: 9-14. [9] 高闯, 韩果等人硅铝摩尔比对Al-SBA-15介孔分子筛结构和性质的影响[J].石油化工, 2011, 3: 314-318. [10] Myung-gi Seo, Dae-Won Lee et al. Pt/Al-SBA-15 catalysts for hydrocracking of C21-C34 n-paraffin mixture into gasoline and diesel fractions[J]. Fuel, 2015, 143:63-71 [11] Da Jeong Kim, Mou Pal ,Won Seok. Confined growth of highly uniform and single bcc-phased FeCo/graphitic-shell nanocrystals in SBA-15[J]. Microporous and Mesoporous Materials, 2013, 180: 32-39. [12] 吴建民, 孙启民, 张宗森等人. 费托合成铁基催化剂上CO和H2 的吸附特性[J]. 过程工程学报, 2013, 2: 327-332. [13] M.G. Alvarez, R.J. Chiment, D. Tichi, B.O.Santos, Synthesis of tungsten carbide on Al-SBA-15 mesoporous materials by carburization[J]. Microporous and Mesoporous Materials, 2016, 219: 19-28. [14] Lin Zhu, Hongxia Qu, Qiangfei Zhou. Direct synthesis, characterization and catalytic performance of Al-Fe-SBA-15 materials in selective catalytic reduction of NO with NH3[J]. Catalysis Communications, 2016, 73: 118-122. [15] Cristina Ochoa-Hernandez, Yongxing Yanga, Patricia Pizarro, et al. Hydrocarbons production through hydrotreating of methyl esters over Ni and Co supported on SBA-15 and Al-SBA-15[J]. Catalysis Today, 2013, 210: 81-88. [16] Micha#322; Moritz, Ma#322;gorzata Geszke-Moritz. Amine-modified SBA-15 and MCF mesoporous molecular sieves as promising sorbents for natural antioxidant. Modeling of caffeic acid adsorption[J]. Materials Science and Engineering C, 2016, 61: 411-421. [17] Xiaodong Zhang, Han Dong, Yin Wang. Study of catalytic activity at the Ag/Al-SBA-15 catalysts for CO oxidation and selective CO oxidation[J]. Chemical Engineering Journal, 2016, 283: 1097-1107. [18] K. Chandra Mouli, Kapil Soni, Ajay Dalai. Effect of pore diameter of Ni#8211;Mo/Al-SBA-15 catalysts on the hydrotreating of heavy gas oil[J]. Applied Catalysis A: General, 2011, 404: 21-29. [19] 曹崇江, 刘晓庚, 陈晓荣等. Pt/Fe双金属Fischer-Tropsch催化剂的设计、合成及表征[J]. 物理化学学报, 2013, 11: 2475-2480. [20] Akbar Zare, Ahad Zare, Mehdi Shiva, Ali Akbar Mirzaei. Effect of calcination and reaction conditions on the catalytic performance of Co#8211;Ni/Al2O3 catalyst for CO hydrogenation[J]. Journal of Industrial and Engineering Chemistry, 2013, 19: 1858-1868. [21] F.G. Botes, J.W. Niemantsverdriet, J. van de Loosdrecht. A comparison of cobalt and iron based slurry phase Fischer#8211;Tropsch synthesis[J]. Catalysis Today, 2015, 2013: 112-120. [22] 杨敬贺, 赵博, 赵华博等. 磷化铁/石墨烯纳米复合物的制备及其在F-T合成反应中的应用[J]. 化学学报, 2013, 71: 1365-1368. [23] 孙裕苹, 沈健, 朱金柱, 张哗. Nb-SBA-15的制备及催化氧化脱硫的研究[J]. 精细石油化工, 2012, 6: 68-71. [24] Xiaowei Zhang, Ni Huang, Ge Wang. Synthesis of highly loaded and well dispersed CuO/SBA-15 via an ultrasonic post-grafting method and its application as a catalyst for the direct hydroxylation of benzene to phenol[J]. Microporous and Mesoporous Materials, 2013, 177: 47-53. [25] Renfeng Nie, Hong Lei, Saiyong Pan, Lina Wang. Core#8211;shell structured CuO#8211;ZnO@H-ZSM-5 catalysts for CO hydrogenation to dimethyl ether[J]. Fuel, 2012, 96: 419-425. [26] Guohui Yang, Montree Thongkam, Tharapong Vitidsant, et al. A double-shell capsule catalyst with core#8211;shell-like structure for one-step exactly controlled synthesis of dimethyl ether from CO2 containing syngas[J]. Catalysis Today, 2011, 171: 229-235. [27] 高闯, 韩果, 孙晓艳. 硅铝摩尔比对Al-SBA-15介孔分子筛结构和性质的影响[J]. 石油化工, 2015, 3: 314-318. [28] Myung-gi Seo, Dae-Won Lee, Kwan-Young Lee, Dong Ju Moon. Pt/Al-SBA-15 catalysts for hydrocracking of C21#8211;C34 n-paraffin mixture into gasoline and diesel fractions[J]. Fuel, 2015, 143: 63-71. [29] Zhenping Qu, Xiaodong Zhang, Fangli Yu. Role of the Al chemical environment in the formation of silver species and its CO oxidation activity[J]. Journal of Catalysis, 2015, 321: 113-122. [30] Aijun Duan, Xin Zhang, Zhen Zhao, Hong E. Synthesis of NiMo catalysts supported on mesoporous Al-SBA-15 withdifferent morphologies and their catalytic performance of DBT HDS[J]. Applied Catalysis B: Environmental, 2015, 165: 269-284. [31] 李祥珍, 王晓钟, 刘瑜, 陈伟, 黄璐. 介孔材料Al-SBA-15的合成研究进展[J]. 化工进展, 2013, 7: 1555-1563.

3. 毕业设计（论文）进程安排

2016年2月21日~2016年3月1日 查阅文献，了解课题背景及研究意义，撰写开题报告； 完成外文文献翻译及论文的文献综述部分。

2016年3月1日~2016年4月15日 制备钴基费托合成催化剂al-sba-15载体。

2016年4月15日~2016年5月10日 对所制备的载体进行表征，结合文献及实验对表征结果进行分析。