1. 毕业设计（论文）的内容和要求

本课题要求在查阅文献的基础上，使用XRD、BET、XPS等分析技术对用溶胶凝胶法制得的钙钛矿材料SrCo0.6Ti0.4Ox在苯酚降解前后进行了较为系统的比较研究，以及考究整个反应条件对SrCo0.6Ti0.4Ox的性能的影响，并对反应中的动力学及机理进行基础的研究。

课题要求： 1、学会采用各种文献检索手段对特定课题进行检索的方法，培养阅读中外文献资料的能力； 2、完成SrCo0.6Ti0.4Ox 粉体的制备； 3、对材料进行表征； 4、对材料在过氧硫酸盐体系中苯酚降解过程进行测试。

2. 参考文献

[1] Yang G, Su C, Chen Y, Dong F, Tade MO, Shao Z. Cobalt-free SrFe0.9Ti0.1O3#8722;δ as a high-performance electrode material for oxygen reduction reaction on doped ceria electrolyte with favorable CO2 tolerance. Journal of the European Ceramic Society 2015;35:2531-9. [2] Taran OP, Ayusheev AB, Ogorodnikova OL, Prosvirin IP, Isupova LA, Parmon VN. Perovskite-like catalysts LaBO3 (B=Cu, Fe, Mn, Co, Ni) for wet peroxide oxidation of phenol. Applied Catalysis B: Environmental 2016;180:86-93. [3] Yao Y, Lu F, Zhu Y, Wei F, Liu X, Lian C, et al. Magnetic core-shell CuFe2O4@C3N4 hybrids for visible light photocatalysis of Orange II. Journal of hazardous materials 2015;297:224-33. [4] Su C, Wang W, Chen Y, Yang G, Xu X, Tade MO, et al. SrCo0.9Ti0.1O3-delta As a New Electrocatalyst for the Oxygen Evolution Reaction in Alkaline Electrolyte with Stable Performance. ACS applied materials interfaces 2015;7:17663-70. [5] Shi B-N, Wan J-F, Liu C-T, Yu X-J, Ma F-W. Synthesis of CoFe2O4/MCM-41/TiO2 composite microspheres and its performance in degradation of phenol. Materials Science in Semiconductor Processing 2015;37:241-9. [6] Ren Y, Lin L, Ma J, Yang J, Feng J, Fan Z. Sulfate radicals induced from peroxymonosulfate by magnetic ferrospinel MFe2O4 (M=Co, Cu, Mn, and Zn) as heterogeneous catalysts in the water. Applied Catalysis B: Environmental 2015;165:572-8. [7] He J, Sun H, Indrawirawan S, Duan X, Tade MO, Wang S. Novel polyoxometalate@g-C(3)N(4) hybrid photocatalysts for degradation of dyes and phenolics. Journal of colloid and interface science 2015;456:15-21. [8] Duan X, O'Donnell K, Sun H, Wang Y, Wang S. Sulfur and Nitrogen Co-Doped Graphene for Metal-Free Catalytic Oxidation Reactions. Small 2015;11:3036-44. [9] Saputra E, Muhammad S, Sun H, Patel A, Shukla P, Zhu ZH, et al. α-MnO2 activation of peroxymonosulfate for catalytic phenol degradation in aqueous solutions. Catalysis Communications 2012;26:144-8. [10] Shukla PR, Wang S, Sun H, Ang HM, Tad#233; M. Activated carbon supported cobalt catalysts for advanced oxidation of organic contaminants in aqueous solution. Applied Catalysis B: Environmental 2010;100:529-34. [11] Shukla P, Wang S, Singh K, Ang HM, Tad#233; MO. Cobalt exchanged zeolites for heterogeneous catalytic oxidation of phenol in the presence of peroxymonosulphate. Applied Catalysis B: Environmental 2010;99:163-9. [12] Wang Y, Sun H, Ang HM, Tad#233; MO, Wang S. 3D-hierarchically structured MnO2 for catalytic oxidation of phenol solutions by activation of peroxymonosulfate: Structure dependence and mechanism. Applied Catalysis B: Environmental 2015;164:159-67. [13] Wang Y, Sun H, Ang HM, Tad#233; MO, Wang S. Magnetic Fe3O4/carbon sphere/cobalt composites for catalytic oxidation of phenol solutions with sulfate radicals. Chemical Engineering Journal 2014;245:1-9. [14] Sun H, Ang HM, Tad#233; MO, Wang S. Co3O4 nanocrystals with predominantly exposed facets: synthesis, environmental and energy applications. Journal of Materials Chemistry A 2013;1:14427. [15] Liang H, Ting YY, Sun H, Ang HM, Tade MO, Wang S. Solution combustion synthesis of Co oxide-based catalysts for phenol degradation in aqueous solution. Journal of colloid and interface science 2012;372:58-62. [16] Liang H, Sun H, Patel A, Shukla P, Zhu ZH, Wang S. Excellent performance of mesoporous Co3O4/MnO2 nanoparticles in heterogeneous activation of peroxymonosulfate for phenol degradation in aqueous solutions. Applied Catalysis B: Environmental 2012;127:330-5.

3. 毕业设计（论文）进程安排

3月份： 阅读文献和熟悉实验室所有仪器设备。

4-5月份： 进行srco0.6ti0.4ox用于过氧硫酸盐体系中苯酚溶液的降解实验，对sct0.4的降解性能的影响因素进行研究，并对材料进行一系列表征。

6月份： 对实验数据进行总结，查漏补缺，撰写毕业论文。