1. 毕业设计（论文）的内容和要求

高分子染料具有良好的成膜性、耐迁移、耐溶剂和不易被人体吸收等优良性能，在染色、涂料印花和涂料染色方面具有较好的应用。

本课题拟通过沉淀聚合法合成低分子量的聚丙烯酸，以聚丙烯酸为原料，通过接枝n,n-二乙基间苯二胺，合成聚(丙烯酸-co-(n-(3-二乙氨基)苯基)丙烯酰胺)(da大分子中间体)。

以da大分子中间体为偶合组分，与苯胺类重氮盐和杂环芳胺类重氮盐偶合合成非水溶性da聚丙烯酸大分子染料paac-dar1，并将其应用于涂料染色和涂料印花。

2. 参考文献

[1]周小明,张淑芬.聚丙烯酸大分子染料的合成与应用[J].染料与染色.2013,4:50-2 [2]李志强,赵焱,陈敏.色素炭黑表面聚丙烯酸接枝改性制备染料[J].四川大学学报(自然科学版),2003,2:40-48 [3]陈一飞,杨郭英,沈丁华.聚丙烯酸系合成增稠剂印花糊料的应用[J].江苏丝绸,2003,3:24-28 [4]李莎,刘根起等.黄原胶接枝聚丙烯酸水凝胶的合成及吸附性能#8212;对亚甲基蓝染料的吸附行为[D].西北工业大学,2013 [5]张淑芬,杨锦宗.化学改性法合成高分子染料的研究[D].大连理工大学精细化工国家重点实验室,2014 [6]杨秀菊,蒲云平,倪良.聚丙烯酸钠-硅溶胶的合成及其对阳离子金黄染料的吸附[J].化工环保,2012,32(2):25-29 [7]Bhattacharyya, Ruma.Removal of congo red and methyl violet from water using nano clay filled composite hydrogels of poly acrylic acid and polyethylene glycol[J].Chemical Engineering Journal,2015,2:260-266 [8]Nguyen,Kim-Truc.Poly(acrylic acid)-capped and dye-loaded graphene oxide-mesoporous silica: a nano-sandwich for two-photon and photoacoustic dual-mode imaging[J].Particle and Particle Systems Characterization,2014,31:10-18 [9]Narayanan.Robust polymeric hydrogel using rod-like amidodiol as crosslinker: Studies on adsorption kinetics and mechanism using dyes as adsorbate[J].Journal of Applied Polymer Science,2014,131:18-32 [10]Liu Jinshui,Liu Guoning,Liu Wenxiu.Preparation of water-soluble β-cyclodextrin/poly(acrylic acid)/graphene oxide nanocomposites as new adsorbents to remove cationic dyes from aqueous solutions[J].Chemical Engineering Journal,2014,14:257-262 [11]Wan Decheng.Charge selective encapsulation by polymeric micelles with cationic, anionic, or zwitterionic cores[J].Journal of Polymer Science,Part A: Polymer Chemistry,2012,50(7):149-156 [12]Hamri Salah.Erythrosine/triethanolamine system to elaborate crosslinked poly(2-hydroxyethylmethacrylate): UV-photopolymerization and swelling studies[J].Macromolecular Symposia,2014:336-342 [13]Hamaloglu.A new method for the synthesis of monodisperse-porous titania microbeads by using polymethacrylate microbeads as template[J].Microporous and Mesoporous Materials,2015:207-215

3. 毕业设计（论文）进程安排

2015.12.01-2015.12.12 与学生见面，布置任务，对论文说明。

2015.12.15-2015.12.26 下达任务书，查阅资料。

2015.12.29-2016.01.23 查阅资料，完善研究方案，完成外文翻译、文献综述和开题报告。