1. 毕业设计（论文）的内容和要求

内容与要求：合成基于四苯丁二烯结构单元的构筑配体，并与金属自组装得到一系列MOFs发光材料，研究其荧光性能，以期其在分子识别及检测方面具有良好的应用前景

2. 参考文献

(1) Cui, Y. J.; Yue, Y. F.; Qian, G. D.; Chen, B. L., "Luminescent Functional Metal-Organic Frameworks" Chem. Rev. 2012, 112, 1126-1162. (2) Kreno, L. E.; Leong, K.; Farha, O. K.; Allendorf, M.; Van Duyne, R. P.; Hupp, J. T., "Metal-Organic Framework Materials as Chemical Sensors" Chem. Rev. 2012, 112, 1105-1125. (3) Li, Y.; Zhang, S. S.; Song, D. T., "A Luminescent metal-organic framework as a turn-on sensor for DMF vapor" Angew. Chem. Int. Ed. 2013, 52, 710-713. (4) Takashima, Y.; Martinez, V.; Furukawa, S.; Kondo, M.; Shimomura, S.; Uehara, H.; Nakahama, M.; Sugimoto, K.; Kitagawa, S., "Molecular decoding using luminescence from an entangled porous framework " Nat. Commun., 2011, 2, 168. (5) Luo, J. D.; Xie, Z. L.; Lam, J. W. Y.; Cheng, L.; Chen, H. Y.; Qiu, C. F.; Kwok, H. S.; Zhan, X. W.; Liu, Y. Q.; Zhu, D. B.; Tang, B. Z., "Aggregation-induced emission of 1-methyl-1,2,3,4,5-pentaphenylsilole" Chem. Commun. 2001, 1740-1741. (6) Hong, Y. N.; Lam, J. W. Y.; Tang, B. Z., "Aggregation-induced emission" Chem. Soc. Rev. 2011, 40, 5361-5388. (7) Liu, Y.; Tang, Y. H.; Barashkov, N. N.; Irgibaeva, I. S.; Lam, J. W. Y.; Hu, R. R.; Birimzhanova, D.; Yu, Y.; Tang, B. Z., "Fluorescent Chemosensor for Detection and Quantitation of Carbon Dioxide Gas" J. Am. Chem. Soc. 2010, 132, 13951-13953. (8) Shustova, N. B.; Ong, T. C.; Cozzolino, A. F.; Michaelis, V. K.; Griffin, R. G.; Dinca, M., "Phenyl Ring Dynamics in a Tetraphenylethylene-Bridged Metal-Organic Framework: Implications for the Mechanism of Aggregation-Induced Emission" J. Am. Chem. Soc. 2012, 134, 15061-15070. (9) Zhang, M.; Feng, G.; Song, Z.; Zhou, Y.-P.; Chao, H.-Y.; Yuan, D. Tan, T. T. Y.; Guo Z.; Hu, Z.; Tang, B. Z.; Liu, B.; Zhao D., ”Two-Dimensional Metal#8722;Organic Framework with Wide Channels and Responsive Turn-On Fluorescence for the Chemical Sensing of Volatile Organic Compounds” J. Am. Chem. Soc. 2014, 136, 7241-7244. (10) Guo, Y.; Feng, X.; Han, T.; Wang, S.; Lin, Z.; Dong, Y.; Wang, B., ”Tuning the Luminescence of Metal#8722;Organic Frameworks for Detection of Energetic Heterocyclic Compounds” J. Am. Chem. Soc. 2014, 136, 15485-15488.

3. 毕业设计（论文）进程安排

1月15日之前：开题工作，包括文献综述及外文文献翻译等 2月22日至2月29日：文献查阅，制定相关合成路线 3月1日至5月22日：合成构筑配体及将其与金属自组装得到MOFs，并测定配体及MOFs的发光性能 5月23至5月29日：整理总结实验结果及数据 5月30日至6月5日：撰写毕业论文及修改、完善，准备论文答辩