SBA-15介孔分子筛固载金属酞菁催化氧化芳甲基类化合物任务书
2020-06-01 16:02:05
1. 毕业设计(论文)的内容和要求
芳甲基类化合物的氧化产物是医药、农药、材料及其他精细化学品的重要中间体[1]。
全世界对芳甲基类化合物的氧化产物的年需求呈逐年上升的趋势。
因此,研究芳甲基类化合物氧化的方法是十分必要的。
2. 参考文献
[1] W. Partenheimer. Methodology and scope of metal/bromide autoxidation of hydrocarbons [J]. Catalysis Today 1995, 23, 69-158. [2] Alexander B. Sorokin. Phthalocyanine Metal Complexes in Catalysis [J]. Chem. Rev. 2013, 113, 8152#8722;8191. [3] Xufeng Song, et al. Highly Efficient, Mild, Bromide-Free and Acetic Acid-Free Dioxygen Oxidation of p-Nitrotoluene to p-Nitrobenzoic Acid with Metal Phthalocyanine Catalysts [J]. Organic Process Research Development 2005, 9, 297-301. [4] Ernst S, et al. Immobilization and catalytic properties of perfluorinated ruthenium phthalocyanine complexes in MCM-41 type molecular sieves [J]. Microporous and Mesoporous Materials, 1999,27(2-3):355-363. [5] Bartels O, et al. Immobilization and photo catalytic properties of phthalocyanines anchored to the surface of Si-MCM-41 and SBA-15 [J]. Stud. Surf. Sci. Catal. 2004, 154, 2884#8211;2892. [6] Yanjie Zhang, et al. Copper(II)-Substituted Polyoxotungstates Immobilized n Amine-Functionalized SBA-15: Efficient HeterogeneousCatalysts for Liquid Phase Oxidative Reaction[J], Catal Lett ,2016,146:2468#8211;2477.
3. 毕业设计(论文)进程安排
起讫日期 设计(论文)各阶段工作内容 备 注 2017.12.16-2017.2.1 查找阅读文献,设计方案 2017.2.2-2017.2.20 确定方案,学习实验过程和操作 2017.2.21-2017.4.30 独立实验,合成催化剂并测试其活性 2017.5.1-2017.5.30 处理数据,撰写论文 2017.5.30- 修改论文并完成答辩