1. 毕业设计（论文）的内容和要求

功能配合物是当今配位化学的研究热点之一。

亚铜簇合物作为一类特殊的多核配合物，因其新颖多样的结构以及优异独特的物理化学性质引起了人们的广泛兴趣，国内外多个课题组在亚铜簇合物的结构调控、可控光致发光等方面已进行了大量研究。

近年来人们发现，亚铜簇合物对乌尔曼c-n偶联反应有机反应具有较优的催化活性，其簇结构、金属中心及配体等可协同提高催化活性。

2. 参考文献

[1] Mayukh Deb, Dheeraj Kumar, Jatinder Singh, and Anil J. Elias. Unprecedented Formation of π#8209;Copper Complexes during Sonogashira Coupling: Synthesis of a Unique, Recyclable, Ethynyl Ferrocene Derived Cu(I) Speci#64257;c Ligand [J].Organometallics. 2016, 35, 1086-1091 [2] Alex C. Bissember, Rylan J. Lundgren, Sidney E. Creutz, Jonas C. Peters, and Gregory C. Fu. Transition-Metal-Catalyzed Alkylations of Amines with Alkyl Halides: Photoinduced, Copper-Catalyzed Couplings of Carbazoles [J]. Homogeneous Catalysis. 2013, 52, 5129 #8211;5133 [3] Wei Ji, Jian Qu, Su Jing, Dunru Zhu and Wei Huang. Copper(I) halide clusters based upon ferrocenylchalcogenoether ligands: donors, halides and semi-rigidity effects on the geometry and catalytic activity [J]. Dalton Trans., 2016, 45, 1016 [4] Cheng-Yun Gu, Su Jing, Wei Ji , Zhi-Wen Li. Group 6 metal carbonyl complexes of 1,5-diselena[5]ferrocenophane:Synthesis, characterization, crystallographic and electrochemical study[J].Inorganica Chimica Acta ,363 (2010), 1604#8211;1606

3. 毕业设计（论文）进程安排

见附件