1. 毕业设计（论文）的内容和要求

1、合成La-ZSM-5、Ce-ZSM-5、La-Ce-ZSM-5分子筛载体 2、制备PtSn/ La-ZSM-5催化剂、PtSn/ Ce-ZSM-5催化剂、PtSn/ La-Ce-ZSM-5催化剂 3、探究不同载体 、Pt/Sn原子比、稀土元素的添加量对催化剂丙烷脱氢性能的影响；进行PtSn/M-ZSM-5催化剂稳定性实验。

2. 参考文献

[1] Zhang Y, Zhou Y, Huang L, et al. Sn-Modified ZSM-5 As Support for Platinum Catalyst in Propane Dehydrogenation[J]. Industrial Engineering Chemistry Research. 2011, 50(13): 7896-7902. [2] Li H L Z S. Influence of the Alkali Treatment of HZSM-5 Zeolite on Catalytic Performance of PtSn-Based Catalyst for Propane Dehydrogenation[J]. 中国炼油与石油化工：英文版. 2013(2): 11-18. [3] 韩伟，潘相米，谭亚南.Na2CO3处理制备复合孔ZSM-5分子筛及其丙烷脱氢制丙烯的催化性能[J]. 化工进展. 2016, 35(b11): 174-178. [4] Xue M, Zhou Y, Zhang Y, et al. Effect of cerium addition on catalytic performance of PtSnNa/ZSM-5 catalyst for propane dehydrogenation[J]. Journal of Natural Gas Chemistry. 2012, 21(3): 324-331. [5] Kaneko S, Arakawa T, Ohshima M, et al. Dehydrogenation of Propane Combined with Selective Hydrogen Combustion over Pt-Sn Bimetallic Catalysts[J]. Applied Catalysis A General. 2009, 365(1): 80-87. [6] 邱安定. 不同介质中合成的S n-Z SM-5及其作为丙烷脱氢催化剂载体的研究[J]. 精细石油化工进展. 2005, 6(7): 24-26. [7] Zhang Y, Xue M, Zhou Y, et al. Propane dehydrogenation over Ce-containing ZSM-5 supported platinum#8211;tin catalysts: Ce concentration effect and reaction performance analysis[J]. RSC Advances. 2016, 6(35): 29410-29422. [8] 付佳，傅吉全. 不同载体对Pt-Sn催化剂丙烷催化脱氢性能影响[J]. 工业催化. 2014(01): 44-47. [9] 董文生，王浩静，王心葵，等. 不同载体的PtSn催化剂上丙烷脱氢性能的研究[J]. 天然气化工. 1999(03): 11-14. [10] Yu C, Ge Q, Xu H, et al. Propane dehydrogenation to propylene over Pt-based catalysts[J]. Catalysis Letters. 2006, 112(3-4): 197-201. [11] 王秀玲. 分子筛载体对Pt-Sn-Na三组分丙烷脱氢催化剂性能的影响[J]. 石油化工. 2012, 41(12): 1346-1350. [12] Treesukol P, Srisuk K, Limtrakul J, et al. Nature of the Metal#8722;Support Interaction in Bifunctional Catalytic Pt/H-ZSM-5 Zeolite[J]. The Journal of Physical Chemistry B. 2005, 109(24): 11940-11945. [13] 邱安定，李恩霞，范以宁. 载体组成对负载型PtSn/ZSM-5催化剂上丙烷脱氢反应性能的影响[J]. 催化学报. 2007(11): 970-974. [14] Zhang Y, Zhou Y, Huang L, et al. Structure and catalytic properties of the Zn-modified ZSM-5 supported platinum catalyst for propane dehydrogenation[J]. Chemical Engineering Journal. 2015, 270: 352-361. [15] 姜冬宇，吴文海，吴省. 低碳烷烃脱氢Pt系催化剂的研究进展[J]. 化学世界. 2014, 12(6): 373-378. [16] Feng J, Zhang M, Yang Y. Dehydrogenation of Propane on Pt or PtSn Catalysts with Al2O3 or SBA-15 Support[J]. Chinese Journal of Chemical Engineering. 2014, 22(11-12): 1232-1236. [17] Long L, Lang W, Yan X, et al. Yttrium-modified alumina as support for trimetallic PtSnIn catalysts with improved catalytic performance in propane dehydrogenation[J]. Fuel Processing Technology. 2016, 146: 48-55. [18] 郭秋双，蔡奇，孙彦民，等. 低碳烷烃脱氢催化剂的研究进展[J]. 无机盐工业. 2016, 48(8): 11-15. [19] Gartner CA, van Veen AC, Lercher JA (2013) Oxidative dehydrogenation of ethane: common principles and mechanistic aspects. ChemCatChem 5:3196#8211;3217 [20] D. Rodr#237;guez, J. S#225;nchez, G. Arteaga, Effect of tin and potassium addition on the nature of platinum supported on silica, J. Mol. Catal. A Chem. 228 (2005) 309#8211;317.

3. 毕业设计（论文）进程安排

起讫日期 设计（论文）各阶段工作内容 备 注 2017.12.25-2018.1.17 查阅资料，完成开题报告 2017.2.26-2017.3.15 确定方案，学习实验过程和操作 2017.3.16-2017.5.20 独立实验，合成产物并进行结构表征 2017.5.21-2017.5.30 数据整理，书写论文，制作PPT 2017.6.1-2017.6.5 修改论文并定稿