1. 毕业设计（论文）的内容和要求

本论文的内容主要有如下几个内容： (1）通过查阅文献设计确定合成目标产物； （2）设计并优化合适的实验方法，并将实验结果进行表征； （3）将目标产物进行一系列电化学性能测试。

2. 参考文献

参考文献 [1]Schmidt V H, Lanceros-M#233;ndez S, Meschia S C, et al. Anomalous and normal protonic conductivity in Cs1#8722;x(NH4)xH2PO4,Cs1#8722;x(ND4)xD2PO4, and K1#8722; x(NH4)x H2PO4[J]. Solid State Ionics Diffusion Reactions, 1999, 125(1#8211;4):147-157. [2]Zhang X , Wang Q , Ma Z , et al. Synthesis, Structure, Multiband Optical, and Electrical Conductive Properties of a 3D Open Cubic Framework Based on [Cu8Sn6S24](z-) Clusters.[J]. Inorganic Chemistry, 2015, 54(11):5301-8. [3]Zhang D , Li G , Peng Y , et al. Synthesis of a Ternary Thiostannate with 3D Channel Decorated by Hydronium for High Proton Conductivity[J]. Inorganic Chemistry, 2017, 56(1):208-212. [4]Luo H B , Ren L T , Ning W H , et al. Robust Crystalline Hybrid Solid with Multiple Channels Showing High Anhydrous Proton Conductivity and a Wide Performance Temperature Range[J]. Advanced Materials, 2016, 28(8):1663-1667.

3. 毕业设计（论文）进程安排

[5]Feng P , Bu X , Zheng N . The Interface Chemistry Between Chalcogenide Clusters and Open Framework Chalcogenides[J]. Cheminform, 2005, 36(29):0-0. [6]Li J R , Huang X Y . [(Me)2NH2]0.75[Ag1.25SnSe3]: A three-dimensionally microporous chalcogenide exhibiting framework flexibility upon ion-exchange[J]. Dalton Transactions, 2011, 40(17):4387. [7]Sarma D , Malliakas C D , Subrahmanyam K S , et al. K2xSn4-xS8-x (x=0.65-1): A new metal sulfide for rapid and selective removal of Cs , Sr2 and UO22 ions[J]. Chemical Science, 2016, 7(2):1121. [8]Ding N , Kanatzidis M G . Selective incarceration of caesium ions by Venus flytrap action of a flexible framework sulfide[J]. Nature Chemistry, 2010, 2(3):187-191. [9]Manos M J , Chrissafis K , Kanatzidis M G . Unique Pore Selectivity for Cs and Exceptionally High NH4 Exchange Capacity of the Chalcogenide Meterial K6Sn[Zn4Sn4S17].[J]. Journal of the American Chemical Society, 2006, 37(40):0-0. [10]Nanfeng Z , Xianhui B , Pingyun F . Synthetic design of crystalline inorganic chalcogenides exhibiting fast-ion conductivity[J]. Nature, 2003, 35(7):428-32. [11]王国明, 杨国煜, 无机化学学报., 2006, 22, 1360. [12]陆栋．《中国大百科全书》74卷（第二版）物理学：中国大百科全书出版社，2009－07：300页 [13]刘志明，吴也平，金丽梅．应用物理化学：化学工业出版社，2009.08 [14]蒋晓辉．最新新型工程材料生产新技术应用与新产品开发研制及行业技术标准实用大全 十 材料分析测试卷：学苑音像出版社，2004.11 [15]尤立省. 锗氧、锗硫簇合物的合成及性质[D]. 苏州大学, 2013.