有机磷酸盐催化开环聚合任务书
2020-06-24 19:48:49
1. 毕业设计(论文)的内容和要求
1.文献查阅 掌握文献查阅的一般方法,学会在中国期刊网、维普数据库、超星数字图书馆、美国化学学会(acs)数据库、英国皇家化学学会(rcs)数据库、elseiver、isi chemistry server、ei、ca 等检索资源上查阅关于课题相关文献。
2.文献阅读及综述 阅读与课题相关的外文及中文文献,了解国内外的研究动态,撰写文献综述。
3.明确实验任务,拟定实验方案 根据所查阅文献的内容,确定实验内容及方案,拟定科学可行的研究计划。
2. 参考文献
[1] Parra A, Reboredo S, Martin Castro A M, et al. Metallic organophosphates as catalysts in asymmetric synthesis: A return journey[J]. Org. Biomol. Chem., 2012, 10(26): 5001-5020. [2] Parmar D, Sugiono E, Raja S, et al. Complete field guide to asymmetric BINOL-phosphate derived Br#248;nsted acid and metal catalysis: History and classification by mode of activation; Br#248;nsted acidity, hydrogen bonding, ion pairing, and metal phosphates[J]. Chem. Rev., 2014, 114(18): 9047-9153. [3] Piedra-Arroni E, Amgoune A, Bourissou D. Dual catalysis: new approaches for the polymerization of lactones and polar olefins[J]. Dalton Trans., 2013, 42(25): 9024-9029. [4] Piedra-Arroni E, Brignou P, Amgoune A, et al. A dual organic/organometallic approach for catalytic ring-opening polymerization[J]. Chem. Commun., 2011, 47(35): 9828-9830. [5] Naumann S, Wang D. Dual Catalysis Based on N-Heterocyclic Olefins for the Copolymerization of Lactones: High Performance and Tunable Selectivity[J]. Macromolecules, 2016, 49(23): 8869-8878. [6] Naumann S, Scholten P B V, Wilson J A, et al. Dual catalysis for selective ring-opening polymerization of lactones: Evolution toward simplicity[J]. J. Am. Chem. Soc., 2015, 137(45): 14439-14445. [7] Saito T, Aizawa Y, Tajima K, et al. Organophosphate-catalyzed bulk ring-opening polymerization as an environmentally benign route leading to block copolyesters, end-functionalized polyesters, and polyester-based polyurethane[J]. Polym. Chem., 2015, 6(24): 4374-4384. [8] Wu J C, Yu T L, Chen C T, et al. Recent developments in main group metal complexes catalyzed/initiated polymerization of lactides and related cyclic esters[J]. Coord. Chem. Rev., 2006, 250(5-6): 602-626. [9] Ottou W N, Sardon H, Mecerreyes D, et al. Update and challenges in organo-mediated polymerization reactions[J]. Prog. Polym. Sci., 2015, 56: 64-115. [10] J#233;r#244;me C, Lecomte P. Recent advances in the synthesis of aliphatic polyesters by ring-opening polymerization[J]. Adv. Drug Del. Rev., 2008, 60(9): 1056-1076.
3. 毕业设计(论文)进程安排
2017.12.25~2018.1.15 确定课题,下达任务书,查阅文献,做好开题前期工作 2015.1.15~2018.2.15 查阅文献,做出研究方案,完成外文翻译和开题报告 2015.2.16~2015.3.31 总结前一阶段工作,完成中期自检和中期汇报,确定下一阶段目标 2015.4.1~2015.4.30 扩展课题研究范围,改进实验方案,对数据整理分析,撰写论文 2015.5.1~2015.6.1 完善毕业论文 2015.6.1~2015.6.10 准备毕业答辩