1. 毕业设计（论文）的内容和要求

1．文献查阅 掌握文献查阅的一般方法，学会使用计算机在中国期刊网，维普数据库，超星数字图书馆等中文数据库,美国化学学会（acs）数据库，ca，sci等外文数据库检索资源上查阅相关的文献。

2．文献阅读及综述 阅读与课题相关的外文及中文文献，了解羰基化反应机理和反应工艺的国内外研究动态，撰写文献综述。

3．明确实验任务，拟定实验方案 根据所查阅文献的内容，确定实验内容及方案，拟定科学可行的研究计划。

2. 参考文献

[1] Souma, Y. and H. Kawasaki, Synthesis of tert.-Alkanoic acid catalyzed by Cu(CO)n and Ag(CO)2 under atmospheric pressure. Catalysis Today, 1997. 36(1): p. 91-97. [2] 陈静, 付宏祥, and 童进, 二异丁烯催化氢酯基化反应制异壬酸酯. 精细化工, 2001(02): p. 109-111. [3] 赵修华, et al., Koch羰基化反应合成羧酸及其工业应用前景. 化工进展, 1999(06): p. 23-26 36-2. [4] 李金恒 and 江焕峰, 过渡金属催化的烯烃羰基化反应现状与进展. 化学通报, 2000(02): p. 17-23. [5] Lin, T., X. Meng, and l. Shi, Catalytic hydrocarboxylation of acetylene to acrylic acid using Ni2O3 and cupric bromide as combined catalysts. Vol. 396. 2015. [6] Souma, Y., J. Iyoda, and H. Sano, Carbonylation of Dienes and Diols in the Presence of Copper(I) Carbonyl Catalysts. Bulletin of the Chemical Society of Japan, 1976. 49(11): p. 3291-3295. [7] Lin, T.J., X. Meng, and L. Shi, Ni-exchanged Y-zeolite: An efficient heterogeneous catalyst for acetylene hydrocarboxylation. Applied Catalysis A: General, 2014. 485: p. 163-171. [8] 陶鹏万 and 姚雄生, 叔碳酸的生产与应用. 精细化工原料及中间体, 2005(11): p. 31-33. [9] Beller, M., et al., Progress in hydroformylation and carbonylation. Journal of Molecular Catalysis A: Chemical, 1995. 104(1): p. 17-85. [10] Elman, A. and A. Batov, Olefin hydrocarboxylation under mild conditions in nickel complex solutions. Vol. 49. 2008. 386-390. [11] Kirillova, M., A.M. Kirillov, and A. J.a#8364;#8230;L. Pombeiro, Metal‐Free and Copper‐Promoted Single‐Pot Hydrocarboxylation of Cycloalkanes to Carboxylic Acids in Aqueous Medium. Vol. 351. 2009. 2936-2948. [12] Kirillova, M., A. M Kirillov, and A. J L Pombeiro, Mild, Single‐Pot Hydrocarboxylation of Gaseous Alkanes to Carboxylic Acids in Metal‐Free and Copper‐Promoted Aqueous Systems. Vol. 16. 2010. 9485-93. [13] Han, M.S., et al., Surface properties of CuCl2/AC catalysts with various Cu contents: XRD, SEM, TG/DSC and CO-TPD analyses. Applied Surface Science, 2003. 211(1): p. 76-81. [14] Lin, T.J., X. Meng, and L. Shi, Catalytic hydrocarboxylation of acetylene to acrylic acid using Ni2O3 and cupric bromide as combined catalysts. Journal of Molecular Catalysis A: Chemical, 2015. 396: p. 77-83. [15] Rybakov, A.A., et al., Theoretical aspects of methanol carbonylation on copper-containing zeolites. Petroleum Chemistry, 2016. 56(3): p. 259-266.

3. 毕业设计（论文）进程安排

2018.12-2019.1 查阅文献，完成开题报告 填写实验进程表 2019.2-2019.3 设计实验方案，初步实验 填写实验进程表 2019.3-2019.5 完善实验方案，系统地进行实验 填写实验进程表 2019.5-2019.6 整理实验数据，总结实验结果 撰写毕业论文 填写实验进程表