高性能氯离子电池正极材料BiOCl的设计合成任务书
2020-05-10 02:44:41
1. 毕业设计(论文)的内容和要求
1. 毕业设计的内容 随着化石资源的枯竭,环境污染的加剧,迫使人们开发新的能源存储体系。
可充放电电池吸引了人们的广泛关注,其中锂离子电池由于具有高的能量密度,功率密度,长的循环寿命,无记忆效应,是目前电动车储能器件的首选。
尽管如此,锂离子电池由于采用易燃的有机液体电解质,正极材料过充时可能会释放氧气,存在燃烧爆炸的潜在危险。
2. 参考文献
1. Zhao, X.; Ren, S.; Bruns, M.; Fichtner, M., Chloride ion battery: A new member in the rechargeable battery family. Journal of Power Sources 2014, 245 (0), 706-711. 2. Zhao, X.; Zhao-Karger, Z.; Wang, D.; Fichtner, M., Metal Oxychlorides as Cathode Materials for Chloride Ion Batteries. Angewandte Chemie International Edition 2013, 52 (51), 13621-13624. 3. Zhang, M.; Shao, C.; Zhang, X.; Liu, Y., Bismuth oxychloride/carbon nanofiber heterostructures for the degradation of 4-nitrophenol. CrystEngComm 2015, 17 (38), 7276-7282. 4. Armelao, L.; Bottaro, G.; Maccato, C.; Tondello, E., Bismuth oxychloride nanoflakes: Interplay between composition-structure and optical properties. Dalton Transactions 2012, 41 (18), 5480-5485. 5. Jiang, J.; Zhao, K.; Xiao, X.; Zhang, L., Synthesis and Facet-Dependent Photoreactivity of BiOCl Single-Crystalline Nanosheets. Journal of the American Chemical Society 2012, 134 (10), 4473-4476. 6. Armand, M.; Tarascon, J. M., Building better batteries. Nature 2008, 451 (7179), 652-657. 7. Bruce, P. G.; Freunberger, S. A.; Hardwick, L. J.; Tarascon, J.-M., Li-O2 and Li-S batteries with high energy storage. Nat Mater 2012, 11 (1), 19-29. 8. Zhang, K.-L.; Liu, C.-M.; Huang, F.-Q.; Zheng, C.; Wang, W.-D., Study of the electronic structure and photocatalytic activity of the BiOCl photocatalyst. Applied Catalysis B: Environmental 2006, 68 (3#8211;4), 125-129. 9. Gao, P.; Zhao, X.; Zhao-Karger, Z.; Diemant, T.; Behm, R. J.; Fichtner, M., Vanadium Oxychloride/Magnesium Electrode Systems for Chloride Ion Batteries. ACS Applied Materials Interfaces 2014, 6 (24), 22430-22435. 10. Zhao, X.; Li, Q.; Zhao-Karger, Z.; Gao, P.; Fink, K.; Shen, X.; Fichtner, M., Magnesium Anode for Chloride Ion Batteries. ACS Applied Materials Interfaces 2014, 6 (14), 10997-11000. 11. Feng, K.; Park, H. W.; Wang, X.; Lee, D. U.; Chen, Z., High Performance Porous Anode Based on Template-Free Synthesis of Co3O4 Nanowires for Lithium-Ion Batteries. Electrochimica Acta 2014, 139, 145-151. 12. Li, Y.; Tan, B.; Wu, Y., Freestanding Mesoporous Quasi-Single-Crystalline Co3O4 Nanowire Arrays. Journal of the American Chemical Society 2006, 128 (44), 14258-14259. 13. Wang, G.; Cao, D.; Yin, C.; Gao, Y.; Yin, J.; Cheng, L., Nickel Foam Supported-Co3O4 Nanowire Arrays for H2O2 Electroreduction. Chemistry of Materials 2009, 21 (21), 5112-5118. 14. Lei, T.; Tian, Y. M.; Wang, G. L.; Yin, J. L.; Gao, Y. Y.; Wen, Q.; Cao, D. X., An Alkaline Al#8211;H2O2 Semi-Fuel Cell Based on a Nickel Foam Supported Co3O4 Nanowire Arrays Cathode. Fuel Cells 2011, 11 (3), 431-435. 15. Deng, H.; Wang, J. W.; Peng, Q.; Wang, X.; Li, Y. D., Controlled hydrothermal synthesis of bismuth oxyhalide nanobelts and nanotubes. Chemistry-a European Journal 2005, 11 (22), 6519-6524.
3. 毕业设计(论文)进程安排
2016.02.22-2016.03.10 查阅文献资料,了解研究背景,完成外文翻译,文献综述和开题报告 2016.3.11-2016.5.16 进行课题实验,结果分析与处理 2016.05.17-2016.06.07 撰写毕业论文,完成审阅与修改 2016.06.07-2016.06.14 制作答辩PPT,进行答辩